Synthesis and Magnetic Properties of Bis-Halobenzene Decamethyldysprosocenium Cations
SC Corner, GK Gransbury, IJ Vitorica-Yrezabal… - Inorganic …, 2024 - ACS Publications
The decamethyldysprosocenium cation,[Dy (Cp*) 2]+(Cp*={C5Me5}), was a target single-
molecule magnet (SMM) prior to the isolation of larger dysprosocenium cations, which have …
molecule magnet (SMM) prior to the isolation of larger dysprosocenium cations, which have …
Pyrrolyl-Bridged Metallocene Complexes: From Synthesis, Electronic Structure, to Single-Molecule Magnetism
F Delano IV, F Benner, S Jang, S Demir - Inorganic Chemistry, 2023 - ACS Publications
The π-and σ-basicity of the pyrrolyl ligand affords several coordination modes. A sterically
encumbering coordination sphere around metal centers may foster new coordination modes …
encumbering coordination sphere around metal centers may foster new coordination modes …
Construction of intermolecular σ-hole interactions in rare earth metallocene complexes using a 2, 3, 4, 5-tetraiodopyrrolyl anion
F Delano, F Benner, S Jang, SM Greer, S Demir - Chemical Science, 2024 - pubs.rsc.org
The generation of noncovalent intermolecular interactions represents a powerful method to
control molecular vibrations and rotations. Combining these with the axial ligand field …
control molecular vibrations and rotations. Combining these with the axial ligand field …
Syntheses and structures of bimetallic rare-earth complexes supported by pyrrolyl ligands and their high performance in isoprene polymerization
FH Wang, SQ She, Y Tao, XR Wang, CH Chu… - Journal of Molecular …, 2022 - Elsevier
The reactions of pyrrole with rare-earth metal amides [(Me 3 Si) 2 N] 3 RE (μ-Cl) Li (THF) 3
produced the bimetallic rare earth metal amido complexes (RE= Y (1), Nd (2), Yb (3)) in high …
produced the bimetallic rare earth metal amido complexes (RE= Y (1), Nd (2), Yb (3)) in high …