Recent advances in luminescent lanthanide based Single-Molecule Magnets

J Long, Y Guari, RAS Ferreira, LD Carlos… - Coordination Chemistry …, 2018 - Elsevier
Abstract Luminescent lanthanide-based Single-Molecule Magnets (SMM) are multifunctional
molecule-based materials that combine luminescence and magnetic properties in the same …

Luminescent Schiff-base lanthanide single-molecule magnets: The association between optical and magnetic properties

J Long - Frontiers in chemistry, 2019 - frontiersin.org
Luminescent Single-Molecule Magnets (SMM) belong to a new class of multifunctional
molecule-materials that associate luminescence and slow relaxation of their magnetization …

High symmetry or low symmetry, that is the question–high performance Dy (III) single-ion magnets by electrostatic potential design

WB Sun, PF Yan, SD Jiang, BW Wang, YQ Zhang… - Chemical …, 2016 - pubs.rsc.org
A series of mononuclear lanthanide Zn–Dy–Zn type single-molecule magnets (SMMs) were
synthesized and magnetically characterized. The four molecules ([Zn2 (L1) 2DyCl3]· 2H2O …

A Low‐Symmetry Dysprosium Metallocene Single‐Molecule Magnet with a High Anisotropy Barrier

T Pugh, NF Chilton, RA Layfield - … Chemie International Edition, 2016 - Wiley Online Library
The single‐molecule magnet (SMM) properties of the isocarbonyl‐ligated dysprosium
metallocene [Cp* 2Dy {μ‐(OC) 2FeCp}] 2 (1Dy), which contains a rhombus‐shaped Dy2Fe2 …

Ab initio prediction of tunneling relaxation times and effective demagnetization barriers in kramers lanthanide single-molecule magnets

D Aravena - The Journal of Physical Chemistry Letters, 2018 - ACS Publications
Single-molecule magnets (SMMs) are promising candidates for molecule-based quantum
information devices. Their main limitation is their cryogenic operative temperature. To …

Exploring the Influence of Diamagnetic Ions on the Mechanism of Magnetization Relaxation in {CoIII2LnIII2} (Ln = Dy, Tb, Ho) “Butterfly” Complexes

KR Vignesh, SK Langley, KS Murray… - Inorganic …, 2017 - ACS Publications
The synthesis and magnetic and theoretical studies of three isostructural heterometallic
[CoIII2LnIII2 (μ3-OH) 2 (o-tol) 4 (mdea) 2 (NO3) 2](Ln= Dy (1), Tb (2), Ho (3))“butterfly” …

Heterometallic 3d–4f single molecule magnets containing diamagnetic metal ions

A Chakraborty, J Goura, P Kalita, A Swain… - Dalton …, 2018 - pubs.rsc.org
Molecular nano magnets such as single-molecule magnets (SMMs) are a class of
coordination complexes with numerous potential applications such as information storage …

Effect of Ligand Substitution around the DyIII on the SMM Properties of Dual-Luminescent Zn–Dy and Zn–Dy–Zn Complexes with Large Anisotropy Energy Barriers: A …

JP Costes, S Titos-Padilla, I Oyarzabal… - Inorganic …, 2016 - ACS Publications
The new dinuclear ZnII–DyIII and trinuclear ZnII–DyIII-ZnII complexes of formula [(LZnBrDy
(ovan)(NO3)(H2O)](H2O)· 0.5 (MeOH)(1) and [(L1ZnBr) 2Dy (MeOH) 2](ClO4)(3)(L and L1 …

Role of the Diamagnetic Zinc (II) Ion in Determining the Electronic Structure of Lanthanide Single‐Ion Magnets

A Upadhyay, C Das, S Vaidya, SK Singh… - … A European Journal, 2017 - Wiley Online Library
Four complexes containing DyIII and PrIII ions and their LnIII–ZnII analogs have been
synthesized in order to study the influence that a diamagnetic ZnII ion has on the electronic …

Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling

T Pugh, NF Chilton, RA Layfield - Chemical Science, 2017 - pubs.rsc.org
Single-molecule magnets (SMMs) are coordination compounds that exhibit magnetic
bistability below a characteristic blocking temperature. Research in this field continues to …