Photoredox catalysis has recently emerged as a powerful synthetic platform for accessing
complex chemical structures through non-traditional bond disconnection strategies that …

The review covers various aspects of fluorinated cycloalkyl (C3− C7) building blocks for drug
discovery, including their synthesis, key physicochemical properties, and biological and …

The synthesis of unnatural, tertiary amino acids is a challenging task. While decarboxylation–
radical addition has been an important strategy for their formation, the use of alkyl radicals …

Enantioenriched unnatural amino acids represent a prevalent motif in organic chemistry,
with profound applications in biochemistry, medicinal chemistry, and materials science …

Alkyl radicals generated via an acridine photocatalyzed decarboxylation reaction of
feedstock carboxylic acids engage with a range of cyclic imine–BF3 complexes to provide α …

Peptides can act as targeting molecules, analogously to oligonucleotide aptamers and
antibodies. They are particularly efficient in terms of production and stability in physiological …

Difluoroboryl complexes obtained from N-acyl hydrazones upon brief treatment with boron
trifluoride and allylic silane serve as efficient acceptors of alkyl radicals. The reaction of the …

An operationally simple protocol for the photocatalytic carbamoylation of imines is reported.
Easily available, bench-stable 4-amido Hantzsch ester derivatives serve as precursors to …

Herein, we disclose an expedient visible-light-mediated, organophotoredox-catalyzed
multicomponent synthesis of unnatural amino acids using a Katritzky salt, glyoxal …

Palladium catalysis induced by visible-light irradiation is a promising tool for promoting
unusual chemical transformations. We describe the development of excited-state palladium …