Imaging the dynamics of catalysed surface reactions by in situ scanning electron microscopy

C Barroo, ZJ Wang, R Schlögl, MG Willinger - Nature Catalysis, 2020 - nature.com
Analytical methods that provide direct real-space information about the dynamics of
catalysed reactions often require simplified model systems and operate under high-vacuum …

Atom probe tomography for catalysis applications: a review

C Barroo, AJ Akey, DC Bell - Applied Sciences, 2019 - mdpi.com
Atom probe tomography is a well-established analytical instrument for imaging the 3D
structure and composition of materials with high mass resolution, sub-nanometer spatial …

Resolving multifrequential oscillations and nanoscale interfacet communication in single-particle catalysis

Y Suchorski, J Zeininger, S Buhr, M Raab… - Science, 2021 - science.org
In heterogeneous catalysis research, the reactivity of individual nanofacets of single
particles is typically not resolved. We applied in situ field electron microscopy to the apex of …

From atomistic to collective dynamics: Bridging gaps in gas-phase electron microscopy for catalysis

TW Hansen, M Willinger - MRS Bulletin, 2023 - Springer
Catalysis is a highly complex phenomenon involving fundamental processes on multiple
length scales. The full-scale complexity of catalysis is only poorly understood, and how …

Nanoscale perspectives of metal degradation via in situ atom probe tomography

SV Lambeets, EJ Kautz, MG Wirth, GJ Orren… - Topics in …, 2020 - Springer
We report a unique in situ instrument development effort dedicated to studying gas/solid
interactions relevant to heterogeneous catalysis and early stages of oxidation of materials …

Pattern Formation in Catalytic H2 Oxidation on Rh: Zooming in by Correlative Microscopy

J Zeininger, P Winkler, M Raab, Y Suchorski… - ACS …, 2022 - ACS Publications
Spatio-temporal nonuniformities in H2 oxidation on individual Rh (hkl) domains of a
polycrystalline Rh foil were studied in the 10–6 mbar pressure range by photoemission …

Directional gateway to metal oxidation: 3D chemical mapping unfolds oxygen diffusional pathways in rhodium nanoparticles

SV Lambeets, T Visart de Bocarmé… - The Journal of …, 2020 - ACS Publications
The interaction of oxygen with a reactive metal is ubiquitous, yet the precise atomic-level
mechanisms and pathways leading to the formation of a surface oxide are not well …

Structure reactivity relationships during N2O hydrogenation over Au-Ag alloys: A study by field emission techniques

L Jacobs, C Barroo, N Gilis, SV Lambeets, E Genty… - Applied Surface …, 2018 - Elsevier
To make available atomic oxygen at the surface of a catalyst is the key step for oxidation
reactions on Au-based catalysts. In this context, Au-Ag alloys catalysts exhibit promising …

Nonlinear behavior during NO2 hydrogenation on a nanosized Pt-Rh catalyst sample

C Barroo, Y De Decker, L Jacobs… - Applied Surface Science, 2017 - Elsevier
Automotive pollution control crucially relies on the reactivity of metal alloy catalysts.
Understanding how the chemistry of an alloy compares with that of pure metals forms a …

Dynamic processes on gold-based catalysts followed by environmental microscopies

E Genty, L Jacobs, T Visart de Bocarmé, C Barroo - Catalysts, 2017 - mdpi.com
Since the early discovery of the catalytic activity of gold at low temperature, there has been a
growing interest in Au and Au-based catalysis for a new class of applications. The …