The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

Acyl Suzuki cross-coupling involves the coupling of an organoboron reagent with an acyl
electrophile (acyl halide, anhydride, ester, amide). This review provides a timely overview of …

While ketones are among the most versatile functional groups, their synthesis remains
reliant upon reactive and low‐abundance starting materials. In contrast, amide formation is …

This Article describes the development of a base-free, nickel-catalyzed decarbonylative
coupling of carboxylic acid fluorides with diboron reagents to selectively afford aryl boronate …

While acid fluorides can readily be made from widely available or biomass‐feedstock‐
derived carboxylic acids, their use as functional groups in metal‐catalyzed cross‐coupling …

Carbamoyl Fluoride-Enabled Enantioselective Ni-Catalyzed Carbocarbamoylation of
Unactivated Alkenes | Journal of the American Chemical Society ACS ACS Publications …

The expansion of chemical space associated with ubiquitous motifs is key to unleash new
properties and functions. In this context, alkynamides, prevalent in numerous drugs and …

Ligand-controlled non-decarbonylative and decarbonylative conversions of acyl fluorides
were developed using a Pd (OAc) 2/Et3SiH combination. When tricyclohexylphosphine …

A fast and simple method for deoxyfluorination of carboxylic acids is presented. The protocol
employs commodity chemicals (PPh3, NBS, fluoride), affording products in excellent yields …

We describe a novel reagent system to obtain acyl fluorides directly from three different
functional group precursors: carboxylic acids, aldehydes, or alcohols. The transformation is …