Chiral sulfoxides: advances in asymmetric synthesis and problems with the accurate determination of the stereochemical outcome

J Han, VA Soloshonok, KD Klika, J Drabowicz… - Chemical Society …, 2018 - pubs.rsc.org
Chiral sulfoxides are in extremely high demand in nearly every sector of the chemical
industry concerned with the design and development of new synthetic reagents, drugs, and …

Metallo (salen) complexes as versatile building blocks for the fabrication of molecular materials and devices with tuned properties

C Freire, M Nunes, C Pereira, DM Fernandes… - Coordination Chemistry …, 2019 - Elsevier
Abstract The [M (salen)] complexes (M= transition metal such as V, Cr, Mn, Fe, Co, Ni, Cu,
Pd) are high versatile coordination compounds, that can be easily immobilised in solid …

One-step hydrothermal synthesis of chiral carbon dots with high asymmetric catalytic activity for an enantioselective direct aldol reaction

S Liu, Y He, Y Liu, S Wang, Y Jian, B Li… - Chemical …, 2021 - pubs.rsc.org
Chiral carbon dots are prepared by a simple and one-step hydrothermal reaction at 180° C
for 2 h using citric acid and D-proline as precursors, which show high asymmetric catalytic …

Synthesis, structural properties, biosafety and applications of chiral mesoporous silica nanostructures

K Gou, Y Wang, L Xie, X Guo, Y Guo, J Ke, L Wu… - Chemical Engineering …, 2021 - Elsevier
Chiral mesoporous silica nanoparticles (CMSNs) are important members of mesoporous
silica nanoparticles (MSNs) family. They not only exhibit prominent physicochemical …

CO2-Switchable Single-Chain Polymeric Nanoparticles Enable Gas-Controllable Reaction Separation for Asymmetric Catalysis in Water

S Liu, M Tang, J Pang, J Hu, W Chen… - ACS Sustainable …, 2022 - ACS Publications
Water-soluble single-chain polymeric nanoparticles (SCPNs), which isolated catalytic sites
within a hydrophobic interior, made water-incompatible organometallic catalysis highly …

An Overview of the challenges and progress of synthesis, characterization and applications of plugged sba-15 materials for heterogeneous catalysis

M Shakeri, ZA Khatami Shal, P Van Der Voort - Materials, 2021 - mdpi.com
A new generation of SBA-15, plugged SBA-15, was initially synthesized in 2002 using extra
silica precursors (Si/organic template molar ratios≈ 80–140) in the gel mixture. The plugged …

FDU-12-C encapsulated t-Bu (R, R) Co II (salen) as a cathode catalyst for asymmetric electrocarboxylation of 1-phenylethyl chloride with CO 2

Y Wang, R Xiong, LT Wang, H Liu, JX Lu… - Catalysis Science & …, 2023 - pubs.rsc.org
The synthesis of high value-added organic carboxylic acids, especially chiral carboxylic
acids, from the electrochemical fixation of CO2 with organic molecules under mild conditions …

A covalently anchored Pd (II)-Schiff base complex over a modified surface of mesoporous silica SBA-16: an efficient and reusable catalyst for the Heck-Mizoroki …

M Niakan, Z Asadi, M Masteri-Farahani - Colloids and Surfaces A …, 2018 - Elsevier
A new heterogeneous palladium catalyst was prepared by covalent anchoring of a
palladium-(II)-Schiff base complex onto the mesoporous cage-like material SBA-16. Several …

Controlled synthesis of chiral carbon dots with high asymmetric catalytic properties and reproducibility for direct aldol reactions: The impact of functional groups of …

J Luo, S Wang, Y Ding, J Shen, C Xu - Carbon, 2024 - Elsevier
The controlled synthesis of carbon dots (CDs) has been a key scientific problem in the field
of catalysis. In this study, chiral CDs from different carbon sources were prepared using the …

An efficient silica supported Chitosan@ vanadium catalyst for asymmetric sulfoxidation and its application in the synthesis of esomeprazole

C Shen, J Qiao, L Zhao, K Zheng, J Jin… - Catalysis Communications, 2017 - Elsevier
A new type of silica supported Chitosan@ vanadium complex was used as a highly active
heterogeneous catalyst for asymmetric oxidation of aryl alkyl sulfides. With the economic …