Electron transport through a (terpyridine) ruthenium metallo-surfactant containing a redox-active aminocatechol derivative

S Amunugama, E Asempa, RC Tripathi… - Dalton …, 2022 - pubs.rsc.org
Aiming to develop a new class of metallosurfactants with unidirectional electron transfer
properties, a (terpyridine) ruthenium complex containing a semiquinone derivative L2 …

Influence of Electronic Configurations on the Modulation of Fermi/Orbital Junction Energies for Directional Electron Transport through 3d1, 3d3, and 3d5 …

ADKI Weeraratne, N Rani, S Amunugama… - The Journal of …, 2022 - ACS Publications
Two new metallosurfactants containing the 3d1 vanadyl (IV) and 3d3 chromium (III) ions
bound to the phenylenediamine-bridged phenolate-rich ligand LN2O2 were designed …

Influence of Peripheral and Ancillary Changes on the Electron Transport of HS3d5 FeIII Metallosurfactants – Substituents, Chain Length, Subphase Polarity, and …

G Kirui, W Kaushalya, SS Perera… - The Journal of …, 2024 - ACS Publications
Our ongoing efforts to design metallosurfactants capable of directional electron transport led
to pondering on the effects of peripheral changes, and the development of 3d5 FeIII systems …

Electrochemical quantification of corrosion mitigation on iron surfaces with gallium (III) and zinc (II) metallosurfactants

ADKI Weeraratne, CC Hewa-Rahinduwage, L Luo… - Langmuir, 2020 - ACS Publications
We have recently described a new potential use for Langmuir–Blodgett films of surfactants
containing redox-inert metal ions in the inhibition of corrosion and have shown good …

Influence of nitro substituents on the redox, electronic, and proton reduction catalytic behavior of phenolate-based [N 2 O 3]-type cobalt (iii) complexes

D Basu, S Mazumder, KK Kpogo, CN Verani - Dalton Transactions, 2019 - pubs.rsc.org
We report on the synthesis, redox, electronic, and catalytic behavior of two new cobalt (III)
complexes, namely [CoIII (L1) MeOH](1) and [CoIII (L2) MeOH](2). These species contain …

A molecular approach for mitigation of aluminum pitting based on films of zinc (II) and gallium (III) metallosurfactants

ADKI Weeraratne… - … A European Journal, 2019 - Wiley Online Library
The use of metallosurfactants to prevent pitting corrosion of aluminum surfaces is discussed
based on the behavior of the metallosurfactants [ZnII (LN2O2) H2O](1) and [GaIII …

[图书][B] Induction And Prevention Of Electron Transport In Langmuir-Blodgett Films Of 3d-Based Metallosurfactants: Studies On Current Rectification And Corrosion …

ADKI Weeraratne - 2021 - search.proquest.com
The work reported in this thesis focused on the use of redox-active metallosurfactants for
current rectification and redox-innocent metallosurfactants for corrosion inhibition. These …

Applications of Metallosurfactants Towards Directional Electron Transport in Au| Lb| Au Junctions and Metal Recovery by Ion Flotation

A Cousino - 2023 - search.proquest.com
Surfactants are a highly versatile group of molecules that find widespread application in
various fields, including detergents, emulsifiers, and cosmetics. They are characterized by …

[图书][B] Development of Terpyridine-Based Metallosurfactants for Directional Electron Tunneling

S Amunugama - 2022 - search.proquest.com
The molecular electronics field is a multidisciplinary area that addresses the utilization of
molecules as the basic unit of electronic components. Depending on the characteristics of …