Use of bromine and bromo-organic compounds in organic synthesis

I Saikia, AJ Borah, P Phukan - Chemical reviews, 2016 - ACS Publications
Bromination is one of the most important transformations in organic synthesis and can be
carried out using bromine and many other bromo compounds. Use of molecular bromine in …

Enantioselective catalytic aziridinations and asymmetric nitrene insertions into CH bonds

P Müller, C Fruit - Chemical reviews, 2003 - ACS Publications
Aziridines are the nitrogen analogues of epoxides and exhibit similar reactivity patterns as
electrophilic reagents. 1 They undergo highly regio-and stereoselective transformations and …

Catalytic methods for metal carbene transformations

MP Doyle - Chemical Reviews, 1986 - ACS Publications
The synthetic uses of organicdiazo compounds for carbenoid transformations have
undergone a renais-sance in recent years as a result of the development of new transition …

Amidation of saturated C− H bonds catalyzed by electron-deficient ruthenium and manganese porphyrins. A highly catalytic nitrogen atom transfer process

XQ Yu, JS Huang, XG Zhou, CM Che - Organic Letters, 2000 - ACS Publications
Amidation of a variety of hydrocarbons with PhI NTs catalyzed by ruthenium and manganese
meso-tetrakis (pentafluorophenyl) porphyrins 1 and 2 afforded N-substituted amides in up to …

Recent advances in metal-mediated carbon-nitrogen bond formation reactions: aziridination and amidation

JA Halfen - Current Organic Chemistry, 2005 - ingentaconnect.com
This review describes recent progress in the development of homogeneous, metal-
mediated, catalytic pathways to synthetically valuable aziridines and sulfonamides. Areas of …

Iron (IV) corroles are potent catalysts for aziridination of olefins by Chloramine-T

L Simkhovich, Z Gross - Tetrahedron Letters, 2001 - Elsevier
Iron(IV) corroles are potent catalysts for aziridination of olefins by Chloramine-T -
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Utilization of N− X bonds in the synthesis of N-Heterocycles

S Minakata - Accounts of chemical research, 2009 - ACS Publications
Nitrogen-containing heterocycles such as aziridines, pyrrolidines, piperidines, and
oxazolines frequently show up as substructures in natural products. In addition, some of …

Iron (III) porphyrin catalyzed aziridination of alkenes with bromamine-T as nitrene source

R Vyas, GY Gao, JD Harden, XP Zhang - Organic Letters, 2004 - ACS Publications
Iron (III) porphyrin complexes Fe (Por) Cl are effective catalysts for aziridination of alkenes
using bromamine-T as the nitrene source. The catalytic system can operate under mild …

Investigations in the transition metal catalyzed aziridination of olefins, amination, and other insertion reactions with Bromamine-T as the source of nitrene

BM Chanda, R Vyas, AV Bedekar - The Journal of Organic …, 2001 - ACS Publications
Investigations into the transition metal catalyzed aziridination of olefins with Bromamine-T as
a new source of nitrene is presented in this account. Comparison of Chloramine-T and …

Recent advances in silver‐catalyzed nitrene, carbene, and silylene‐transfer reactions

Z Li, C He - European journal of organic chemistry, 2006 - Wiley Online Library
Silver salts are commonly used as Lewis acids in organic synthesis. Silver complexes can
also exhibit strong oxidation power due to their high oxidation potentials. This review …