Theory of surfactant self-assembly: a predictive molecular thermodynamic approach

R Nagarajan, E Ruckenstein - Langmuir, 1991 - ACS Publications
A thermodynamic treatment of surfactant self-assembly in aqueous media is developed that
allows an a priori quantitative prediction of the aggregation behavior of surfactants, starting …

Molecular‐thermodynamic approach to predict micellization, phase behavior and phase separation of micellar solutions. I. Application to nonionic surfactants

S Puvvada, D Blankschtein - The Journal of chemical physics, 1990 - pubs.aip.org
We present a detailed description of a molecular-thermodynamic approach which consists of
blending a molecular model of micellization with a thermodynamic theory of phase behavior …

Complexation of poly (oxyethylene) in analytical chemistry. A review

T Okada - Analyst, 1993 - pubs.rsc.org
The complexation of the polyethers with metal ions is of fundamental and practical
importance. Tn particular, the cyclic polyethers, such as the crown ethers, have received …

Phenomenological theory of equilibrium thermodynamic properties and phase separation of micellar solutions

D Blankschtein, GM Thurston… - The Journal of chemical …, 1986 - pubs.aip.org
A detailed description and generalization of a recently developed theory, which provides
analytic representations of the distribution of micellar species and the equilibrium …

Universal scaling of adsorption of nonionic surfactants on carbonates using cloud point temperatures

S Das, A Katiyar, N Rohilla, Q Nguyen… - Journal of Colloid and …, 2020 - Elsevier
Hypothesis Nonionic surfactants alter the wettability of oil-wet carbonate surfaces to a water-
wet state. The degree of surfactant adsorption is expected to determine the extent of the …

Clouding of a nonionic surfactant: the effect of added surfactants on the cloud point

AS Sadaghiania, A Khan - Journal of colloid and interface science, 1991 - Elsevier
The nonionic surfactant Triton X-100 is soluble in water giving only one isotropic solution
phase at about 32° C. The cloud point (CP) of the aqueous system has been measured over …

Polyethers in inorganic capillary electrophoresis

T Okada - Journal of Chromatography A, 1999 - Elsevier
Various additives are employed in running solutions in capillary electrophoresis (CE) to
enhance separation performance and selectivity. Complexing agents are successfully …

Temperature-induced phase separation of nonionic polyoxyethylated surfactant and application to extraction of metal thiocyanates

T Okada - Analytical chemistry, 1992 - ACS Publications
Poly (oxyethylene)(7.5) nonylphenyl ether Is utilized for the cloud point lon-palr extraction of
thiocyanate complexes of traneltlon-metal Ions. The cloud point of this surfactant Is sensitive …

A transport model for the adsorption of surfactant from micelle solutions onto a clean air/water interface in the limit of rapid aggregate disassembly relative to diffusion …

Q Song, A Couzis, P Somasundaran… - Colloids and Surfaces A …, 2006 - Elsevier
A transport theory and supporting experiments are detailed for the adsorption of surfactant
from micelle solutions onto a clean air/water interface. The study focuses on adsorption from …

On interpreting fluorescence measurements: what does thermodynamics have to say about change in micellar aggregation number versus change in size distribution …

R Nagarajan - Langmuir, 1994 - ACS Publications
Xi), if/g» is large. On the other hand, the aggregation number must be virtually independent
of the total surfactant concentration if/#„is small, close to zero. Equation 10 is a general …