Understanding the electric double-layer structure, capacitance, and charging dynamics

J Wu - Chemical Reviews, 2022 - ACS Publications
Significant progress has been made in recent years in theoretical modeling of the electric
double layer (EDL), a key concept in electrochemistry important for energy storage …

Hierarchical materials from high information content macromolecular building blocks: construction, dynamic interventions, and prediction

L Shao, J Ma, JL Prelesnik, Y Zhou, M Nguyen… - Chemical …, 2022 - ACS Publications
Hierarchical materials that exhibit order over multiple length scales are ubiquitous in nature.
Because hierarchy gives rise to unique properties and functions, many have sought …

Predicting Outcomes of Nanoparticle Attachment by Connecting Atomistic, Interfacial, Particle, and Aggregate Scales

L Liu, BA Legg, W Smith, LM Anovitz, X Zhang… - ACS …, 2023 - ACS Publications
Predicting nanoparticle aggregation and attachment phenomena requires a rigorous
understanding of the interplay among crystal structure, particle morphology, surface …

Physicochemical hydrodynamics of particle diffusiophoresis driven by chemical gradients

JT Ault, S Shin - Annual Review of Fluid Mechanics, 2024 - annualreviews.org
Chemical gradients, the spatial variations in chemical concentrations and components, are
omnipresent in environments ranging from biological and environmental systems to …

Charging dynamics of electrical double layers inside a cylindrical pore: predicting the effects of arbitrary pore size

F Henrique, PJ Zuk, A Gupta - Soft Matter, 2022 - pubs.rsc.org
Porous electrodes are found in energy storage devices such as supercapacitors and
pseudocapacitors. However, the effect of electrode-pore-size distribution on their energy …

Ion correlation-driven like-charge attraction in multivalent salt solutions

NR Agrawal, R Kaur, C Carraro, R Wang - The Journal of Chemical …, 2023 - pubs.aip.org
The electrostatic double layer force is key to determining the stability and self-assembly of
charged colloids and many other soft matter systems. Fully understanding the attractive force …

Diffusioosmosis-driven dispersion of colloids: a Taylor dispersion analysis with experimental validation

BM Alessio, S Shim, A Gupta, HA Stone - Journal of Fluid Mechanics, 2022 - cambridge.org
Diffusiophoresis refers to the movement of colloidal particles in the presence of a
concentration gradient of a solute and enables directed motion of colloidal particles in …

Electrostatic correlation induced ion condensation and charge inversion in multivalent electrolytes

NR Agrawal, R Wang - Journal of Chemical Theory and …, 2022 - ACS Publications
The study of the electrical double layer lies at the heart of colloidal and interfacial science.
The standard mean-field Poisson–Boltzmann (PB) theory is incapable of modeling many …

Diffusiophoresis and diffusioosmosis in tandem: Two-dimensional particle motion in the presence of multiple electrolytes

BM Alessio, S Shim, E Mintah, A Gupta, HA Stone - Physical Review Fluids, 2021 - APS
Diffusiophoresis is the movement of colloidal particles due to a gradient in the concentration
of a solute. Previous studies on diffusiophoresis have focused largely on one-dimensional …

Anion-assisted delivery of multivalent cations to inert electrodes

A Baskin, JW Lawson… - The Journal of Physical …, 2021 - ACS Publications
To understand and control key electrochemical processes—metal plating, corrosion,
intercalation, etc.—requires molecular-scale details of the active species at electrochemical …