Conspectus The discovery of materials capable of storing magnetic information at the level
of single molecules and even single atoms has fueled renewed interest in the slow magnetic …

Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …

Replacing a monoanionic cyclopentadienyl (Cp) ligand in dysprosium single‐molecule
magnets (SMMs) with a dianionic cyclobutadienyl (Cb) ligand in the sandwich complexes …

Recently, the field of molecular magnets has experienced a remarkable result: magnetic
remanence above liquid nitrogen temperatures (> 77 K); this represents the first example of …

The dicarbollide ion, nido‐C2B9H112− is isoelectronic with cyclopentadienyl. Herein, we
make dysprosiacarboranes, namely [(C2B9H11) 2Ln (THF) 2][Na (THF) 5](Ln= Dy, 1Dy) and …

By means of the facile chemistry, structural assembly, and transformation of four
mononuclear Dy (III) complexes, Dy (bpad) 3· CH3OH· H2O (1), Dy (bpad) 2 (H2O) 2· NO3 …

Two new dimeric dysprosium (III) complexes,[Dy2 (HL) 2 (SCN) 2]· 2CH3CN (1) and [Dy2
(HL) 2 (NO3) 2]· 2CH3CN· 2H2O (2), have been assembled using the H3L multidentate …

Single-molecule magnets (SMMs) have attracted much attention due to their potential
applications in molecular spintronic devices. Rare earth SMMs are considered to be the …

Two families of lanthanide metal–organic frameworks (Ln-MOFs), namely {[Ln2L2 (DMF) 4]·
xDMF· yH2O} n (Ln= Ce (1), Pr (2), Sm (3), Eu (4), Gd (5); x= 0, 1; y= 0, 1) and {[Ln2L2 (H2O) …