We present a current, up-to-date review of the surface hopping methodology for solving
nonadiabatic problems, 25 years after Tully published the fewest switches surface hopping …

Conventional nonlinear spectroscopy uses classical light to detect matter properties through
the variation of its response with frequencies or time delays. Quantum light opens up new …

Femtosecond stimulated Raman spectroscopy (FSRS) is an ultrafast nonlinear optical
technique that provides vibrational structural information with high temporal (sub‐50 fs) …

Crossings of electronic potential energy surfaces in nuclear configuration space, known as
conical intersections, determine the rates and outcomes of a large class of photochemical …

Multielectron acceptors are essential components for artificial photosynthetic systems that
must deliver multiple electrons to catalysts for solar fuels applications. The recently …

Light-driven chemical transformations provide a compelling approach to understanding
chemical reactivity with the potential to use this understanding to advance solar energy and …

We describe the development, implementation, and application of a polarizable QM/MM
strategy, based on the AMOEBA polarizable force field, for calculating molecular properties …

Conspectus Femtosecond spectroscopy has revealed coherent wave packet motion time
and time again, but the question as to whether these coherences are necessary for reactivity …

The terms adiabatic and nonadiabatic, respectively, are used in many different contexts.
Whereas in classical thermodynamics, adiabatic refers to processes that occur without any …

Excited-state vibrational dynamics in molecules can be studied by an electronically off-
resonant Raman process induced by a probe pulse with variable delay with respect to an …