Molecular views on mechanisms of Brønsted acid-catalyzed reactions in zeolites
C Chizallet, C Bouchy, K Larmier… - Chemical …, 2023 - ACS Publications
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …
applications of these materials in heterogeneous catalysis, mainly in the fields of …
Carbocation chemistry confined in zeolites: spectroscopic and theoretical characterizations
Acid-catalyzed reactions inside zeolites are one type of broadly applied industrial reactions,
where carbocations are the most common intermediates of these reaction processes …
where carbocations are the most common intermediates of these reaction processes …
Layered double hydroxide membrane with high hydroxide conductivity and ion selectivity for energy storage device
Membranes with fast and selective ions transport are highly demanded for energy storage
devices. Layered double hydroxides (LDHs), bearing uniform interlayer galleries and …
devices. Layered double hydroxides (LDHs), bearing uniform interlayer galleries and …
Selectivity descriptors for the direct hydrogenation of CO2 to hydrocarbons during zeolite-mediated bifunctional catalysis
Cascade processes are gaining momentum in heterogeneous catalysis. The combination of
several catalytic solids within one reactor has shown great promise for the one-step …
several catalytic solids within one reactor has shown great promise for the one-step …
Experimental and theoretical assessments of aluminum proximity in MFI zeolites and its alteration by organic and inorganic structure-directing agents
The molecular structure and cationic charge density of organic and inorganic structure-
directing agents (SDAs) influence the siting and arrangement of Al substituted in zeolite …
directing agents (SDAs) influence the siting and arrangement of Al substituted in zeolite …
Elemental zoning enhances mass transport in zeolite catalysts for methanol to hydrocarbons
Mass transport limitations in zeolite catalysts pose major hurdles for their optimal
performance in diverse chemical reactions. Most approaches to reduce these restrictions …
performance in diverse chemical reactions. Most approaches to reduce these restrictions …
Water structures on acidic zeolites and their roles in catalysis
Q Liu, JA van Bokhoven - Chemical Society Reviews, 2024 - pubs.rsc.org
The local reaction environment of catalytic active sites can be manipulated to modify the
kinetics and thermodynamic properties of heterogeneous catalysis. Because of the unique …
kinetics and thermodynamic properties of heterogeneous catalysis. Because of the unique …
Unravelling the reactivity of framework Lewis acid sites towards methanol activation on H‐ZSM‐5 zeolite with solid‐state NMR spectroscopy
M Hu, C Wang, Y Chu, Q Wang, S Li… - Angewandte Chemie …, 2022 - Wiley Online Library
Understanding the acid sites on zeolites is vital for the establishment of catalyst structure–
activity relationship and exploration of their potential applications in heterogeneous …
activity relationship and exploration of their potential applications in heterogeneous …
Dynamics of heterogeneous catalytic processes at operando conditions
The rational design of high-performance catalysts is hindered by the lack of knowledge of
the structures of active sites and the reaction pathways under reaction conditions, which can …
the structures of active sites and the reaction pathways under reaction conditions, which can …
Influence of active-site proximity in zeolites on Brønsted acid-catalyzed reactions at the microscopic and mesoscopic levels
Zeolites are the catalytic workhorses of various relevant reactions, primarily because of their
acidic properties. However, there have been few studies on unraveling the influence of Al …
acidic properties. However, there have been few studies on unraveling the influence of Al …