Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

This review classifies and summarizes the past 10–15 years of advancements in the field of
metal-involving (ie, metal-mediated and metal-catalyzed) reactions of oximes. These …

Homogeneous Cu/TEMPO catalyst systems (TEMPO= 2, 2, 6, 6-tetramethylpiperidine-N-
oxyl) have emerged as some of the most versatile and practical catalysts for aerobic alcohol …

Selective oxidation reactions are challenging when carried out on an industrial scale. Many
traditional methods are undesirable from an environmental or safety point of view. There is a …

Oxidation from alcohols to carboxylic acids, a class of essential chemicals in daily life,
academic laboratories, and industry, is a fundamental reaction, usually using at least a …

Aerobic alcohol oxidations catalyzed by transition metal salts and aminoxyls are prominent
examples of cooperative catalysis. Cu/aminoxyl catalysts have been studied previously and …

The organic nitroxyl radical, TEMPO (2, 2, 6, 6-tetramethylpiperidine-N-oxyl), finds a variety
of industrial applications for chemical transformations. Because of economic and …

It has been a long time since C–H bond oxidations first attracted chemists' attention. In the
last several decades, C–H bond oxidation has been extensively investigated and applied in …

Abstract Nitroxyl radicals, illustrated by 2, 2, 6, 6-tetramethylpiperidine-N-oxyl (TEMPO),
constitute a versatile class of stable free radicals that are extensively used in metal complex …

2, 2′-Bipyridine-ligated copper complexes, in combination with TEMPO (2, 2, 6, 6-
tetramethylpiperidine-N-oxyl), are highly effective catalysts for aerobic alcohol oxidation …