Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry
The magnetic anisotropy associated with a pentagonal bipyramidal (PBP) coordination
sphere is examined on the basis of experimental and theoretical investigations. The origin …
sphere is examined on the basis of experimental and theoretical investigations. The origin …
Halide mediated modulation of magnetic interaction and anisotropy in dimeric Co (ii) complexes
EM Manohar, S Roy, XL Li, S Tothadi, JG Mok… - Dalton …, 2024 - pubs.rsc.org
The burgeoning interest in the field of molecular magnetism is to perceive the high magnetic
anisotropy in different geometries of metal complexes and hence to draw a magneto …
anisotropy in different geometries of metal complexes and hence to draw a magneto …
Syntheses, characterization, and antimicrobial studies of Ni (II), Cu (II), and Co (III) complexes with an N-pendant azamacrocyclic chelator
L Dey, S Rabi, D Palit, SKS Hazari, ZA Begum… - Journal of Molecular …, 2021 - Elsevier
Abstract Condensation of 1, 2-diamino propane with acetone in the presence of perchloric
acid furnished a 14-membered octamethyl tetraazamacrocycle, Me 8 [14] diene⋅ 2HClO 4 …
acid furnished a 14-membered octamethyl tetraazamacrocycle, Me 8 [14] diene⋅ 2HClO 4 …
Stable and inert macrocyclic cobalt (ii) and nickel (ii) complexes with paraCEST response
P Pérez-Lourido, E Madarasi, F Antal… - Dalton …, 2022 - pubs.rsc.org
We report the synthesis of the macrocyclic ligands 3, 9-PC2AMH (2, 2′-(3, 6, 9-triaza-1 (2,
6)-pyridinacyclodecaphane-3, 9-diyl) diacetamide) and 3, 9-PC2AMtBu (2, 2′-(3, 6, 9-triaza …
6)-pyridinacyclodecaphane-3, 9-diyl) diacetamide) and 3, 9-PC2AMtBu (2, 2′-(3, 6, 9-triaza …
Weak antiferromagnetic interaction in Cu (ii) complex with semi-coordination exchange pathway
We present structural and magnetic studies of complex [Cu (dpt)(NCS) 2], 1a, dpt= bis (3-
aminopropyl) amine. A weak antiferromagnetic interaction mediated by a Cu⋯ π non …
aminopropyl) amine. A weak antiferromagnetic interaction mediated by a Cu⋯ π non …
Mononuclear Heptacoordinated 3d-Metal Helicates as a New Family of Single Ion Magnets
YP Tupolova, DV Korchagin, AS Andreeva… - Magnetochemistry, 2022 - mdpi.com
The series of Co (II), Fe (II), and Ni (II) mononuclear coordination compounds of [CoL (NCS)
2]· 3DMSO (1),[CoL (H2O) 2](ClO4) 2· DMSO (2),[CoL (H2O)(EtOH)][CoCl4]· 2H2O (2a),[FeL …
2]· 3DMSO (1),[CoL (H2O) 2](ClO4) 2· DMSO (2),[CoL (H2O)(EtOH)][CoCl4]· 2H2O (2a),[FeL …
Triple M as Manganese: Medicine, magnetism and macrocycles. Seven-coordinate Mn (II) complexes with pyridine-based macrocyclic ligands
E Zahradnikova, I Císařová, B Drahoš - Polyhedron, 2021 - Elsevier
Manganese, or more accurately manganese (II) complexes, are extensively used in various
scientific and research fields. In this work, we present the preparation and characterization of …
scientific and research fields. In this work, we present the preparation and characterization of …
Synthesis, structural and magnetic properties of cobalt (ii) complexes with pyridine-based macrocyclic ligand containing two pyridine pendant arms
E Zahradníková, C Pichon, C Duhayon, JP Sutter… - RSC …, 2024 - pubs.rsc.org
With the aim of tuning the magnetic anisotropy, a series of Co (II) complexes with the general
formula of complex cations [Co (L) X]+, where X= Br−(1); I−(2); NCO−(3); NCS−(4a); N3−(5) …
formula of complex cations [Co (L) X]+, where X= Br−(1); I−(2); NCO−(3); NCS−(4a); N3−(5) …
A pentagonal bipyramidal Co (II) single-ion magnet based on an asymmetric tetradentate ligand with easy plane anisotropy
XC Huang, W Yong, S Moorthy, ZY Su, JJ Kong… - Polyhedron, 2023 - Elsevier
High-coordinate 3d single-ion magnets (SIMs) especially with pentagonal bipyramidal
geometry as an emerging class of representative molecular magnets have received …
geometry as an emerging class of representative molecular magnets have received …
Effective tuning of magnetic anisotropy in distorted pentagonal bipyramidal Ni (II) complexes via substitution of axial coligands
A series of Ni (II) complexes with pyridine-based macrocyclic ligand L (3, 12, 18-triaza-6, 9-
dioxabicyclo [12.3. 1] octadeca-1 (18), 14, 16-triene) with general formula [Ni (L)(X) 2] …
dioxabicyclo [12.3. 1] octadeca-1 (18), 14, 16-triene) with general formula [Ni (L)(X) 2] …