An open-cage [60] fullerene derivative was prepared through Malaprade oxidation of a
vicinal triol moiety as the key step. Above the 17-membered orifice, there is one carboxyl …

The insertion of ionic compounds into open‐cage fullerenes is a challenging task due to the
electropositive nature of the cavity. The present work reports the preparation of an open …

The optical resolution of open-[60] fullerenes has been limited to only one example since
1998, while the recent advances revealed the excellence of fullerenes as revisited chiral …

Small N-heterocyclic molecules are important scaffolds in the pharmaceutical industry and
most FDA-approved drugs are nitrogen-containing heterocycles. Chemists try to employ iron …

Abstract An open‐cage [60] fullerene was prepared through a multiple‐step sequence
based on peroxide‐mediated cage‐opening reactions. Key steps include repeated C60 …

A general and practical methodology for the preparation of novel vinyl-substituted [60]
fullerene-fused tetrahydrofurans/pyrans/quinolines through palladium-catalyzed …

Heterocyclic orifices in cage-opened fullerene derivatives are regarded as potential ligands
toward metals or ions, being reminiscent of truncated fullerenes as a hypothetical class of …

Redox noninnocent ligands have drawn considerable attention owing to effective interplay
with metal (s) via π–d interactions, enabling magnetic on/off switching as well as redox …

The first example of transition-metal catalyzed multicomponent carboannulation of [60]
fullerene has been developed.[60] Fullerene, 2-(2, 3-allenyl) malonates, and (hetero) aryl …

Abstract Two open‐[60] fullerenols were synthesized through a selective bond cleavage by
reactions with N‐oxide or singlet oxygen. Both open‐[60] fullerenols having a bis (hemiketal) …