[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time
A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …
perspective of how information can be stored. The current bit, occupying few hundreds of …
Metal–metal bond in lanthanide single-molecule magnets
Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …
Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet
Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …
size limit for molecule-based magnetic information storage materials. Their current drawback …
Molecular magnetic hysteresis at 60 kelvin in dysprosocenium
Lanthanides have been investigated extensively for potential applications in quantum
information processing and high-density data storage at the molecular and atomic scale …
information processing and high-density data storage at the molecular and atomic scale …
Symmetry strategies for high performance lanthanide-based single-molecule magnets
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …
High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets
KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018 - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
Single-molecule magnets beyond a single lanthanide ion: the art of coupling
YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …
A dysprosium metallocene single‐molecule magnet functioning at the axial limit
Abstraction of a chloride ligand from the dysprosium metallocene [(Cpttt) 2DyCl](1Dy Cpttt=
1, 2, 4‐tri (tert‐butyl) cyclopentadienide) by the triethylsilylium cation produces the first base …
1, 2, 4‐tri (tert‐butyl) cyclopentadienide) by the triethylsilylium cation produces the first base …
On approaching the limit of molecular magnetic anisotropy: a near‐perfect pentagonal bipyramidal dysprosium (III) single‐molecule magnet
YS Ding, NF Chilton, REP Winpenny… - Angewandte Chemie …, 2016 - Wiley Online Library
We report a monometallic dysprosium complex,[Dy (OtBu) 2 (py) 5][BPh4](5), that shows the
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …
Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications
AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …
research interest in the design and synthesis of artificial porphyrinoids and their metal …