Photopolymerization activated by photobase generators and applications: from photolithography to high-quality photoresists

HW Pei, K Ye, Y Shao, D Chen, ZY Sun, T Gong… - Polymer …, 2024 - pubs.rsc.org
Light-induced polymerization has become a very attractive technology for advanced
manufacturing of polymers. In fact, the photopolymerization processes, and even the final …

Record release of tetramethylguanidine using a green light activated photocage for rapid synthesis of soft materials

KY Chung, A Uddin, ZA Page - Chemical Science, 2023 - pubs.rsc.org
Photocages have enabled spatiotemporally governed organic materials synthesis with
applications ranging from tissue engineering to soft robotics. However, the reliance on high …

Shedding light on cellular dynamics: the progress in developing photoactivated fluorophores

H Wei, M Xie, M Chen, Q Jiang, T Wang, P Xing - Analyst, 2024 - pubs.rsc.org
Photoactivated fluorophores (PAFs) are highly effective imaging tools that exhibit a removal
of caging groups upon light excitation, resulting in the restoration of their bright fluorescence …

Simultaneous Color‐and Dose‐Controlled Thiol–Ene Resins for Multimodulus 3D Printing with Programmable Interfacial Gradients

MT Kiker, EA Recker, A Uddin, ZA Page - Advanced Materials, 2024 - Wiley Online Library
Drawing inspiration from nature's own intricate designs, synthetic multimaterial structures
have the potential to offer properties and functionality that exceed those of the individual …

Onium Photocages for Visible-Light-Activated Poly (thiourethane) Synthesis and 3D Printing

MT Kiker, A Uddin, LM Stevens, CJ O'Dea… - Journal of the …, 2024 - ACS Publications
The lack of chemical diversity in light-driven reactions for 3D printing poses challenges in
the production of structures with long-term ambient stability, recyclability, and breadth in …

Synthesis, UV-curing behaviors and general properties of acrylate-urethane resins prepared from castor oil-based polyols

Y Zhang, J Zhao, J Cai, X Ai, P Zhang, H Hu… - Progress in Organic …, 2024 - Elsevier
Castor oil-based polyols with high single bondOH values are synthesized through the low
odor thiol-ene reaction and then are used for preparing UV-curable acrylate-urethane resins …

Red light activatable photobase generator for rapid thiol-nucleophilic polymerization

WL Koay, E Ye, CLK Lee, XJ Loh, Y Lu… - Materials Today …, 2024 - Elsevier
Photobase generators (PBGs) are molecules capable of releasing reactive bases when
exposed to a photonic field. These compounds have been increasingly used as photolatent …