[HTML][HTML] Bio-oil production from pyrolysis of oil palm biomass and the upgrading technologies: A review

LM Terry, C Li, JJ Chew, A Aqsha, BS How… - Carbon Resources …, 2021 - Elsevier
Oil palm biomass (OPB) represents major portion of the lignocellulosic waste in Malaysia
that can be converted into bio-oil. This review aims to provide important insights in OPB …

Catalytic advancements in carboxylic acid ketonization and its perspectives on biomass valorisation

B Boekaerts, BF Sels - Applied Catalysis B: Environmental, 2021 - Elsevier
Ketonization of (biomass) carboxylic acids is increasingly showing its potential as upgrading
strategy to renewable fuels and chemicals. Due to the growing amount of recent studies, an …

Increasing oxide reducibility: the role of metal/oxide interfaces in the formation of oxygen vacancies

A Ruiz Puigdollers, P Schlexer, S Tosoni… - Acs …, 2017 - ACS Publications
Reducibility is an essential characteristic of oxide catalysts in oxidation reactions following
the Mars–van Krevelen mechanism. A typical descriptor of the reducibility of an oxide is the …

Carbon-increasing catalytic strategies for upgrading biomass into energy-intensive fuels and chemicals

H Li, A Riisager, S Saravanamurugan, A Pandey… - Acs …, 2018 - ACS Publications
Lignocellulosic biomass is the most abundant organic carbon source and has received a
great deal of interest as renewable and sustainable feedstock for the production of potential …

C–O bond activation using ultralow loading of noble metal catalysts on moderately reducible oxides

J Fu, J Lym, W Zheng, K Alexopoulos, AV Mironenko… - Nature Catalysis, 2020 - nature.com
Selective C–O activation of multifunctional molecules is essential for many important
chemical processes. Although reducible metal oxides are active and selective towards …

Ketonization of Carboxylic Acids in Biomass Conversion over TiO2 and ZrO2 Surfaces: A DFT Perspective

G Pacchioni - Acs Catalysis, 2014 - ACS Publications
Carboxylic acids play a fundamental role in the transformation of biomass into liquid fuels
and other useful chemicals. In order to reduce the O/C content of biofuels, carboxylic acids …

Toward Understanding and Controlling Organic Reactions on Metal Oxide Catalysts

V Fung, M Janik, S Crossley, YHC Chin… - The Journal of …, 2023 - ACS Publications
Metal oxides have structurally complex surfaces on which a variety of adsorption site types
can occur, including cation sites, anion sites, oxygen vacancy sites, and Brønsted acid sites …

Hydrogen Adsorption, Dissociation, and Spillover on Ru10 Clusters Supported on Anatase TiO2 and Tetragonal ZrO2 (101) Surfaces

HYT Chen, S Tosoni, G Pacchioni - ACS Catalysis, 2015 - ACS Publications
The scope of this work is to study at atomistic level the mechanism of hydrogen spillover
promoted by metal particles on oxide surfaces. By means of Density Functional Theory …

Experimental and theoretical assessment of the mechanism and site requirements for ketonization of carboxylic acids on oxides

S Wang, E Iglesia - Journal of Catalysis, 2017 - Elsevier
Ketonization of carboxylic acids removes O-atoms and forms new CC bonds, thus providing
routes from sustainable carbon feedstocks to fuels and chemicals. The elementary steps …

Ketonization of oxygenated hydrocarbons on metal oxide based catalysts

R Kumar, N Enjamuri, S Shah, AS Al-Fatesh… - Catalysis Today, 2018 - Elsevier
The ketonization of various renewable biomass-derived oxygenated feedstocks such as
carboxylic acids, aldehydes, alcohols, and esters is presented. As most previous …