Oligo-β-diketones as versatile ligands for use in metallo-supramolecular chemistry: Recent progress and perspectives
Classical β-diketones have long been demonstrated to be excellent chelating ligands for a
wide range of metal ions from across the Periodic Table. More recently, bis-and tris …
wide range of metal ions from across the Periodic Table. More recently, bis-and tris …
[HTML][HTML] The Tripodal Ligand's 4f Complexes: Use in Molecular Magnetism
KE Vostrikova - Inorganics, 2023 - mdpi.com
A predictable type of coordination is a key property of tripodal ligands. Homo-and
heteroleptic lanthanide complexes with tripodal ligands are a representative class of …
heteroleptic lanthanide complexes with tripodal ligands are a representative class of …
Covalency versus magnetic axiality in Nd molecular magnets: Nd-photoluminescence, strong ligand-field, and unprecedented nephelauxetic effect in fullerenes NdM …
W Yang, M Rosenkranz, G Velkos, F Ziegs… - Chemical …, 2024 - pubs.rsc.org
Nd-based nitride clusterfullerenes NdM2N@ C80 with rare-earth metals of different sizes
(M= Sc, Y, Lu) were synthesized to elucidate the influence of the cluster composition, shape …
(M= Sc, Y, Lu) were synthesized to elucidate the influence of the cluster composition, shape …
Increasing the Symmetry around Lanthanide Ions: The Effect on Single-Ion Magnet Behavior and Electronic Structure
JR Thomas, MJ Giansiracusa, RA Mole… - Crystal Growth & …, 2023 - ACS Publications
Bis-capped lanthanide compounds have dominated the single-ion magnet (SIM) field with
little variation in design. Herein, we report the new synthesis of the lanthanide compounds …
little variation in design. Herein, we report the new synthesis of the lanthanide compounds …
Steric hindrance effect of Schiff-base ligands on magnetic relaxation dynamics and emissive behavior of two dinuclear dysprosium complexes
Y Jiang, S Dey, H Ke, Y Yang, L Sun, G Xie, S Chen… - Journal of Rare …, 2023 - Elsevier
The self-assembly reactions between mixed-ligand and tetrahydrate dysprosium acetate in
the presence of mixed organic solvents lead to two structural similar dinuclear dysprosium …
the presence of mixed organic solvents lead to two structural similar dinuclear dysprosium …
Design of Heterometallic {LnIII–MV} (Ln = Dy, Er; M = W, Mo) Molecular Nanomagnets: Protonation Induced Structural Diversification
PD Mao, NT Yao, HY Sun, FF Yan… - Crystal Growth & …, 2022 - ACS Publications
The construction of lanthanide-based molecular magnets by a self-assembly strategy of
multidentate building blocks and functional ligands is continuing to be a hot research topic …
multidentate building blocks and functional ligands is continuing to be a hot research topic …
Structures and magnetic relaxation properties of cyclopentadienyl/β-diketonate/trispyrazolylborate hybridized dysprosium single-molecule magnets
The combination of cyclopentadiene, β-diketonate and tripyrazoylborate ligands with
dysprosium ion afforded five mononuclear compounds:[(Cp) 2 Dy (Tp*)](1Dy),[(Cp) Dy (Tp*) …
dysprosium ion afforded five mononuclear compounds:[(Cp) 2 Dy (Tp*)](1Dy),[(Cp) Dy (Tp*) …
Rapid Spectrometer-Free Luminescence-Based Detection of Tb3+ and Eu3+ in Aqueous Solution for Recovery and Urban Mining
AE Sedykh, JJ Pflug, TC Schäfer… - ACS Sustainable …, 2022 - ACS Publications
A novel and robust procedure was developed for the rapid qualitative and semi-quantitative
detection of trivalent terbium and europium in aqueous solution without significant process …
detection of trivalent terbium and europium in aqueous solution without significant process …
Crystal and electronic structure, thermochemical and photophysical properties of europium-silver sulfate monohydrate AgEu (SO4) 2· H2O
In order to synthesize single crystals of europium-silver double sulfate monohydrate, a
hydrothermal reaction route was used. It was found that the crystallization cannot be …
hydrothermal reaction route was used. It was found that the crystallization cannot be …
Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion …
KA Smirnova, YO Edilova, MA Kiskin… - International Journal of …, 2023 - mdpi.com
Functionalized perfluoroalkyl lithium β-diketonates (LiL) react with lanthanide (III) salts (Ln=
Eu, Gd, Tb, Dy) in methanol to give heterobimetallic Ln-Li complexes of general formula …
Eu, Gd, Tb, Dy) in methanol to give heterobimetallic Ln-Li complexes of general formula …