Promises and pitfalls of Quantitative Structure− Activity Relationship approaches for predicting metabolism and toxicity

E Zvinavashe, AJ Murk… - Chemical research in …, 2008 - ACS Publications
The description of quantitative structure− activity relationship (QSAR) models has been a
topic for scientific research for more than 40 years and a topic within the regulatory …

Bis(1,3-di-tert-butylimidazolin-2-iminato) Titanium Complexes as Effective Catalysts for the Monodisperse Polymerization of Propylene

M Sharma, HS Yameen, B Tumanskii… - Journal of the …, 2012 - ACS Publications
The use of bis (1, 3-di-tert-butylimidazolin-2-iminato) titanium dichloride (1) and dimethyl (2)
complexes in the polymerization of propylene is presented. The complexes were activated …

Synthesis and structure of Group 4 symmetric amidinate complexes and their reactivity in the polymerization of α-olefins

T Elkin, NV Kulkarni, B Tumanskii… - …, 2013 - ACS Publications
The steric properties of various nitrogen substituents on amidines were tuned in order to
obtain group 4 mono-and bis (amidinate) dimethylamido or chloride complexes. The …

Benzimidazolin-2-iminato hafnium complexes: synthesis, characterization, and catalytic addition of alcohols to carbodiimides

M Khononov, H Liu, N Fridman, M Tamm… - …, 2020 - ACS Publications
A series of asymmetric imidazolin-2-iminato and benzimidazolin-2-iminato hafnium (IV)
complexes were synthesized and fully characterized including single-crystal X-ray …

Asymmetric Bis (formamidinate) Group 4 Complexes: Synthesis, Structure and Their Reactivity in the Polymerization of α-Olefins.

NV Kulkarni, T Elkin, B Tumaniskii… - …, 2014 - ACS Publications
A series of asymmetric formamidine ligands bearing different substituents with various steric
and electronic properties on the nitrogen of the N–C–N motif were synthesized. Group 4 bis …

Amidinate group 4 complexes in the polymerization of olefins

T Elkin, MS Eisen - Catalysis Science & Technology, 2015 - pubs.rsc.org
The current perspective will present the use of amidinate group 4 complexes in α-olefin
polymerizations. We will present the structural studies of the complexes bearing various …

Thorium 2-pyridylamidinates: synthesis, structure and catalytic activity towards the cyclo-oligomerization of ε-caprolactone

E Rabinovich, S Aharonovich, M Botoshansky… - Dalton …, 2010 - pubs.rsc.org
Salt metathesis of ThCl4· 3THF with N, N′-bis (trimethylsilyl)-2-pyridyl-lithium-TMEDA (1)
yields bis (N, N′-bis (trimethylsilyl)-2-pyridylamidinate) thorium-chloride (μ-Cl) 2Li …

Lithium Furyl and Pyridyl Amidinates as Building Blocks in Coordination Polymers, Ladder and Cage Structures

S Aharonovich, M Botoshanski, Z Rabinovich… - Inorganic …, 2010 - ACS Publications
Lithium N, N′-bis (trimethylsilyl) heterocyclic amidinate complexes with 3-and 4-pyridyl and
3-furyl carbon substituents were prepared by addition of the corresponding nitriles to LiN …

Organoactinides in the polymerization of ethylene: is TIBA a better cocatalyst than MAO?

E Domeshek, RJ Batrice, S Aharonovich… - Dalton …, 2013 - pubs.rsc.org
The synthesis of two pyridylamidinate bis (N, N '-bis (trimethylsilyl)-2-pyridylamidinate) An (μ-
Cl) 2Li (TMEDA)(An= U (1), Th (2)) complexes is presented. For complex 1 the solid state X …

Titanium bis (amidinates) bearing electron donating pendant arms as catalysts for stereospecific polymerization of propylene

T Elkin, M Botoshansky, RM Waymouth… - Organometallics, 2014 - ACS Publications
A series of titanium bis (amidinate) complexes containing pendant arms as one of the
amidinate N substituents have been prepared and studied in the polymerization of …