Advanced supramolecular design for direct ink writing of soft materials

M Tang, Z Zhong, C Ke - Chemical Society Reviews, 2023 - pubs.rsc.org
The exciting advancements in 3D-printing of soft materials are changing the landscape of
materials development and fabrication. Among various 3D-printers that are designed for soft …

Synthesis and applications of anisotropic nanoparticles with precisely defined dimensions

AK Pearce, TR Wilks, MC Arno… - Nature Reviews Chemistry, 2021 - nature.com
Shape and size play powerful roles in determining the properties of a material; controlling
these aspects with precision is therefore an important, fundamental goal of the chemical …

Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

Alkyne-palladium (II)-catalyzed living polymerization of isocyanides: an exploration of diverse structures and functions

N Liu, L Zhou, ZQ Wu - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Inspired by the perfect helical structures and the resulting exquisite functions of
biomacromolecules, helical polymers have attracted increasing attention in recent years …

Enabling future nanomanufacturing through block copolymer self-assembly: A review

C Cummins, R Lundy, JJ Walsh, V Ponsinet, G Fleury… - Nano Today, 2020 - Elsevier
Self-assembly approaches, eg colloidal, emulsion and polymer phase separation, provide
scientists with an exotic yet direct platform to access technologically desired nanostructures …

Chameleon-like elastomers with molecularly encoded strain-adaptive stiffening and coloration

M Vatankhah-Varnosfaderani, AN Keith, Y Cong… - Science, 2018 - science.org
Active camouflage is widely recognized as a soft-tissue feature, and yet the ability to
integrate adaptive coloration and tissuelike mechanical properties into synthetic materials …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

RNA-polymer hybrids via direct and site-selective acylation with the ATRP initiator and photoinduced polymerization

J Jeong, X Hu, H Murata, G Szczepaniak… - Journal of the …, 2023 - ACS Publications
Combining synthetic polymers with RNA paves the way for creating RNA-based materials
with non-canonical functions. We have developed an acylation reagent that allows for direct …

Architectural code for rubber elasticity: from supersoft to superfirm materials

SS Sheiko, AV Dobrynin - Macromolecules, 2019 - ACS Publications
The current approach to regulating mechanical properties of elastomeric materials is
predominately based on the exploratory mixing of different polymers, solvents, and fillers …