Synergistic dual transition metal catalysis
UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …
enable a reaction between two separately activated substrates, has unlocked a plethora of …
Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation
B Zhao, T Rogge, L Ackermann, Z Shi - Chemical Society Reviews, 2021 - pubs.rsc.org
The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …
decades for the construction of complex molecules from simple, readily available feedstocks …
Cross-coupling of aromatic esters and amides
R Takise, K Muto, J Yamaguchi - Chemical Society Reviews, 2017 - pubs.rsc.org
Catalytic cross-coupling reactions of aromatic esters and amides have recently gained
considerable attention from synthetic chemists as de novo and efficient synthetic methods to …
considerable attention from synthetic chemists as de novo and efficient synthetic methods to …
Decarboxylative reactions with and without light–a comparison
J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …
starting materials for the formation of platform molecules or high-value chemicals. Many …
Decarboxylation as the key step in C− C bond‐forming reactions
C− C bond forming reactions incarnate the core of organic synthesis because of their
fundamental applications to molecular diversity and complexity. In recent years, use of …
fundamental applications to molecular diversity and complexity. In recent years, use of …
Transition‐metal‐catalyzed direct arylation of (hetero) arenes by C H bond cleavage
L Ackermann, R Vicente… - Angewandte Chemie …, 2009 - Wiley Online Library
The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …
undergone rapid development in recent years, and is becoming an increasingly viable …
Decarboxylative coupling reactions: a modern strategy for C–C-bond formation
N Rodríguez, LJ Goossen - Chemical Society Reviews, 2011 - pubs.rsc.org
This critical review examines transition metal-catalyzed decarboxylative couplings that have
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …
Design and optimization of catalysts based on mechanistic insights derived from quantum chemical reaction modeling
Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …
experimental results were obtained. With the rapid development of software and hardware …
The 2‐Pyridyl Problem: Challenging Nucleophiles in Cross‐Coupling Arylations
XAF Cook, A de Gombert, J McKnight… - Angewandte …, 2021 - Wiley Online Library
Azine‐containing biaryls are ubiquitous scaffolds in many areas of chemistry, and efficient
methods for their synthesis are continually desired. Pyridine rings are prominent amongst …
methods for their synthesis are continually desired. Pyridine rings are prominent amongst …
Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways
WI Dzik, PP Lange, LJ Goossen - Chemical Science, 2012 - pubs.rsc.org
This tutorial review provides a comparison between the concepts of catalytic decarboxylative
and decarbonylative couplings for the ipso-substitution of carboxylate groups, and illustrates …
and decarbonylative couplings for the ipso-substitution of carboxylate groups, and illustrates …