Synergistic dual transition metal catalysis

UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation

B Zhao, T Rogge, L Ackermann, Z Shi - Chemical Society Reviews, 2021 - pubs.rsc.org
The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

Cross-coupling of aromatic esters and amides

R Takise, K Muto, J Yamaguchi - Chemical Society Reviews, 2017 - pubs.rsc.org
Catalytic cross-coupling reactions of aromatic esters and amides have recently gained
considerable attention from synthetic chemists as de novo and efficient synthetic methods to …

Decarboxylative reactions with and without light–a comparison

J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …

Decarboxylation as the key step in C− C bond‐forming reactions

T Patra, D Maiti - Chemistry–A European Journal, 2017 - Wiley Online Library
C− C bond forming reactions incarnate the core of organic synthesis because of their
fundamental applications to molecular diversity and complexity. In recent years, use of …

Transition‐metal‐catalyzed direct arylation of (hetero) arenes by C H bond cleavage

L Ackermann, R Vicente… - Angewandte Chemie …, 2009 - Wiley Online Library
The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

N Rodríguez, LJ Goossen - Chemical Society Reviews, 2011 - pubs.rsc.org
This critical review examines transition metal-catalyzed decarboxylative couplings that have
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …

Design and optimization of catalysts based on mechanistic insights derived from quantum chemical reaction modeling

S Ahn, M Hong, M Sundararajan, DH Ess… - Chemical …, 2019 - ACS Publications
Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …

The 2‐Pyridyl Problem: Challenging Nucleophiles in Cross‐Coupling Arylations

XAF Cook, A de Gombert, J McKnight… - Angewandte …, 2021 - Wiley Online Library
Azine‐containing biaryls are ubiquitous scaffolds in many areas of chemistry, and efficient
methods for their synthesis are continually desired. Pyridine rings are prominent amongst …

Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways

WI Dzik, PP Lange, LJ Goossen - Chemical Science, 2012 - pubs.rsc.org
This tutorial review provides a comparison between the concepts of catalytic decarboxylative
and decarbonylative couplings for the ipso-substitution of carboxylate groups, and illustrates …