Redox: Organic robust radicals and their polymers for energy conversion/storage devices

K Hatakeyama-Sato, K Oyaizu - Chemical Reviews, 2023 - ACS Publications
Persistent radicals can hold their unpaired electrons even under conditions where they
accumulate, leading to the unique characteristics of radical ensembles with open-shell …

Significant charge transport effects due to subtle molecular changes in nitroxide radical single crystals

Z Liang, SN Hsu, Y Tan, H Tahir, HJ Kim, K Liu… - Cell Reports Physical …, 2023 - cell.com
Radical-containing materials have received renewed interest due to their charge-conducting
properties. However, most work focuses on macromolecules, while less attention has been …

Porous macroradical epoxy-based supercapacitors

JC Capricho, K Subhani, BX Chai, G Bryant, N Salim… - Polymer, 2022 - Elsevier
Intrinsic p-type conductivity was observed in an otherwise aliphatic epoxy backbone through
derivatization with stable radicals. The conductive potential of this combined radical-epoxy …

Recent advances in open-shell mixed conductors—From molecular radicals to polymers

J Ko, QH Nguyen, QV Thi, Y Joo - Chemical Physics Reviews, 2023 - pubs.aip.org
Mixed conductors have recently garnered attention in the chemical physicist community due
to their distinctive conducting nature and numerous potential applications. These species …

Mapping out the nonconjugated organic radical conductors via chemical or physical pathways

J Ko, I Yu, SY Jeon, D Sohn, SG Im, Y Joo - JACS Au, 2022 - ACS Publications
Stable, nitroxide-based organic radicals have gained tremendous attention in a wide range
of research fields, ranging from solid-state electronics to energy storage devices. While the …

Charge Transport and Magneto-Responsive Properties of Open-Shell Single Crystals

S Debnath, H Yeo, LY Peng, DAJ Hurboda… - Chemistry of …, 2024 - ACS Publications
Nonconjugated open-shell molecules are promising in a host of organic electronic and
spintronic applications due to their abilities to conduct charge and provide magneto …

Conductive Glassy Nonconjugated Open-Shell Radical Polymer with Organosulfur Backbone for Macroscopic Conductivity

QV Thi, QH Nguyen, YS Choi, SY Jeon, BW Boudouris… - JACS Au, 2024 - ACS Publications
Nonconjugated organic radicals with an open-shell radical active group exhibit unique
functionality due to their radical pendant site. Compared with the previously studied doped …