Modeling the formation and growth of atmospheric molecular clusters: A review
Molecular clusters are ubiquitous constituents of the ambient atmosphere, that can grow into
larger sizes forming new aerosol particles. The formation and growth of small clusters into …
larger sizes forming new aerosol particles. The formation and growth of small clusters into …
Atmospheric nanoparticle growth
D Stolzenburg, R Cai, SM Blichner, J Kontkanen… - Reviews of Modern …, 2023 - APS
New particle formation of liquid or solid nanoparticles from gas-phase precursors is a
decisive process in Earth's atmosphere and is considered one of the largest uncertainties in …
decisive process in Earth's atmosphere and is considered one of the largest uncertainties in …
Quantum chemical modeling of organic enhanced atmospheric nucleation: A critical review
J Elm, D Ayoubi, M Engsvang… - Wiley …, 2023 - Wiley Online Library
Aerosol particles are important for our global climate, but the mechanisms and especially the
relative importance of various vapors for new particles formation (NPF) remain uncertain …
relative importance of various vapors for new particles formation (NPF) remain uncertain …
Free energy barrier in the growth of sulfuric acid–ammonia and sulfuric acid–dimethylamine clusters
The first step in atmospheric new particle formation involves the aggregation of gas phase
molecules into small molecular clusters that can grow by colliding with gas molecules and …
molecules into small molecular clusters that can grow by colliding with gas molecules and …
[HTML][HTML] Enhanced growth rate of atmospheric particles from sulfuric acid
In the present-day atmosphere, sulfuric acid is the most important vapour for aerosol particle
formation and initial growth. However, the growth rates of nanoparticles (< 10 nm) from …
formation and initial growth. However, the growth rates of nanoparticles (< 10 nm) from …
An atmospheric cluster database consisting of sulfuric acid, bases, organics, and water
J Elm - Acs Omega, 2019 - ACS Publications
We have collected, recomputed, and compiled a database consisting of 633 unique
atmospherically relevant molecular clusters containing sulfuric acid, bases, oxidized organic …
atmospherically relevant molecular clusters containing sulfuric acid, bases, oxidized organic …
Hydrogen-bond topology is more important than acid/base strength in atmospheric prenucleation clusters
SE Harold, CJ Bready, LA Juechter… - The Journal of …, 2022 - ACS Publications
We explored the hypothesis that on the nanoscale level, acids and bases might exhibit
different behavior than in bulk solution. Our study system consisted of sulfuric acid, formic …
different behavior than in bulk solution. Our study system consisted of sulfuric acid, formic …
Atmospheric clusters to nanoparticles: Recent progress and challenges in closing the gap in chemical composition
JN Smith, DC Draper, S Chee, M Dam, H Glicker… - Journal of Aerosol …, 2021 - Elsevier
Aerosol nanoclusters (AN), defined here as molecular aggregates suspended in a gas with
dimensions between 2 and 10 nm, are the link between substances that we think of as …
dimensions between 2 and 10 nm, are the link between substances that we think of as …
Sulfuric acid as autocatalyst in the formation of sulfuric acid
M Torrent-Sucarrat, JS Francisco… - Journal of the American …, 2012 - ACS Publications
Sulfuric acid can act as a catalyst of its own formation. We have carried out a computational
investigation on the gas-phase formation of H2SO4 by hydrolysis of SO3 involving one and …
investigation on the gas-phase formation of H2SO4 by hydrolysis of SO3 involving one and …
Massive assessment of the binding energies of atmospheric molecular clusters
Quantum chemical studies of the formation and growth of atmospheric molecular clusters
are important for understanding aerosol particle formation. However, the search for the …
are important for understanding aerosol particle formation. However, the search for the …