Modeling the formation and growth of atmospheric molecular clusters: A review

J Elm, J Kubečka, V Besel, MJ Jääskeläinen… - Journal of Aerosol …, 2020 - Elsevier
Molecular clusters are ubiquitous constituents of the ambient atmosphere, that can grow into
larger sizes forming new aerosol particles. The formation and growth of small clusters into …

Atmospheric nanoparticle growth

D Stolzenburg, R Cai, SM Blichner, J Kontkanen… - Reviews of Modern …, 2023 - APS
New particle formation of liquid or solid nanoparticles from gas-phase precursors is a
decisive process in Earth's atmosphere and is considered one of the largest uncertainties in …

Quantum chemical modeling of organic enhanced atmospheric nucleation: A critical review

J Elm, D Ayoubi, M Engsvang… - Wiley …, 2023 - Wiley Online Library
Aerosol particles are important for our global climate, but the mechanisms and especially the
relative importance of various vapors for new particles formation (NPF) remain uncertain …

Free energy barrier in the growth of sulfuric acid–ammonia and sulfuric acid–dimethylamine clusters

T Olenius, O Kupiainen-Määttä, IK Ortega… - The Journal of …, 2013 - pubs.aip.org
The first step in atmospheric new particle formation involves the aggregation of gas phase
molecules into small molecular clusters that can grow by colliding with gas molecules and …

[HTML][HTML] Enhanced growth rate of atmospheric particles from sulfuric acid

D Stolzenburg, M Simon, A Ranjithkumar… - Atmospheric …, 2020 - acp.copernicus.org
In the present-day atmosphere, sulfuric acid is the most important vapour for aerosol particle
formation and initial growth. However, the growth rates of nanoparticles (< 10 nm) from …

An atmospheric cluster database consisting of sulfuric acid, bases, organics, and water

J Elm - Acs Omega, 2019 - ACS Publications
We have collected, recomputed, and compiled a database consisting of 633 unique
atmospherically relevant molecular clusters containing sulfuric acid, bases, oxidized organic …

Hydrogen-bond topology is more important than acid/base strength in atmospheric prenucleation clusters

SE Harold, CJ Bready, LA Juechter… - The Journal of …, 2022 - ACS Publications
We explored the hypothesis that on the nanoscale level, acids and bases might exhibit
different behavior than in bulk solution. Our study system consisted of sulfuric acid, formic …

Atmospheric clusters to nanoparticles: Recent progress and challenges in closing the gap in chemical composition

JN Smith, DC Draper, S Chee, M Dam, H Glicker… - Journal of Aerosol …, 2021 - Elsevier
Aerosol nanoclusters (AN), defined here as molecular aggregates suspended in a gas with
dimensions between 2 and 10 nm, are the link between substances that we think of as …

Sulfuric acid as autocatalyst in the formation of sulfuric acid

M Torrent-Sucarrat, JS Francisco… - Journal of the American …, 2012 - ACS Publications
Sulfuric acid can act as a catalyst of its own formation. We have carried out a computational
investigation on the gas-phase formation of H2SO4 by hydrolysis of SO3 involving one and …

Massive assessment of the binding energies of atmospheric molecular clusters

AB Jensen, J Kubecka, G Schmitz… - Journal of Chemical …, 2022 - ACS Publications
Quantum chemical studies of the formation and growth of atmospheric molecular clusters
are important for understanding aerosol particle formation. However, the search for the …