Use of bromine and bromo-organic compounds in organic synthesis

I Saikia, AJ Borah, P Phukan - Chemical reviews, 2016 - ACS Publications
Bromination is one of the most important transformations in organic synthesis and can be
carried out using bromine and many other bromo compounds. Use of molecular bromine in …

Direct C− H transformation via iron catalysis

CL Sun, BJ Li, ZJ Shi - Chemical Reviews, 2011 - ACS Publications
The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …

Catalytic methods for metal carbene transformations

MP Doyle - Chemical Reviews, 1986 - ACS Publications
The synthetic uses of organicdiazo compounds for carbenoid transformations have
undergone a renais-sance in recent years as a result of the development of new transition …

Enantioselective catalytic aziridinations and asymmetric nitrene insertions into CH bonds

P Müller, C Fruit - Chemical reviews, 2003 - ACS Publications
Aziridines are the nitrogen analogues of epoxides and exhibit similar reactivity patterns as
electrophilic reagents. 1 They undergo highly regio-and stereoselective transformations and …

Recent advances in transition metal-catalyzed sp 3 C–H amination adjacent to double bonds and carbonyl groups

TA Ramirez, B Zhao, Y Shi - Chemical Society Reviews, 2012 - pubs.rsc.org
Transition metal-catalyzed C–H amination at positions adjacent to double bonds and
carbonyl groups is discussed in this critical review. While the focus will center on the recent …

Microwave-accelerated homogeneous catalysis in organic chemistry

M Larhed, C Moberg, A Hallberg - Accounts of chemical research, 2002 - ACS Publications
The efficiency of microwave flash heating in accelerating organic transformations (reaction
times reduced from days and hours to minutes and seconds) has recently been proven in …

More sustainable approaches for the synthesis of N-based heterocycles

NR Candeias, LC Branco, PMP Gois… - Chemical …, 2009 - ACS Publications
More Sustainable Approaches for the Synthesis of N-Based Heterocycles | Chemical Reviews
ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Mechanistic studies of the rhodium-catalyzed direct C–H amination reaction using azides as the nitrogen source

SH Park, J Kwak, K Shin, J Ryu, Y Park… - Journal of the American …, 2014 - ACS Publications
Direct C–H amination of arenes offers a straightforward route to aniline compounds without
necessitating aryl (pseudo) halides as the starting materials. The recent development in this …

Intermolecular Ritter-Type C–H Amination of Unactivated sp3 Carbons

Q Michaudel, D Thevenet, PS Baran - Journal of the American …, 2012 - ACS Publications
Intermolecular Ritter-type C–H amination of unactivated sp3 carbons has been developed.
This new reaction proceeds under mild conditions using readily available reagents and an …

Toward a synthetically useful stereoselective C− H amination of hydrocarbons

C Liang, F Collet, F Robert-Peillard… - Journal of the …, 2008 - ACS Publications
Reaction between a sulfur (VI) compound and an iodine (III) oxidant in the presence of a
catalytic quantity (≤ 3 mol%) of a rhodium (II) catalyst leads to the formation of a chiral …