Dynamic ion correlations in solid and liquid electrolytes: how do they affect charge and mass transport?

NM Vargas‐Barbosa, B Roling - ChemElectroChem, 2020 - Wiley Online Library
Solid and liquid electrolytes for electrochemical energy storage and conversion cells, such
as batteries, supercapacitors and fuel cells, contain often high concentrations of mobile ions …

Colloquium: Understanding ion motion in disordered solids from impedance spectroscopy scaling

DL Sidebottom - Reviews of modern physics, 2009 - APS
ac impedance measurements of ion-conducting glasses provide considerable insight into
the nature of the ionic motions in disordered solids. However, interpreting the ac impedance …

Boosting solid‐state diffusivity and conductivity in lithium superionic argyrodites by halide substitution

P Adeli, JD Bazak, KH Park, I Kochetkov… - Angewandte Chemie …, 2019 - Wiley Online Library
Developing high‐performance all‐solid‐state batteries is contingent on finding solid
electrolyte materials with high ionic conductivity and ductility. Here we report new halide …

Fundamental questions relating to ion conduction in disordered solids

JC Dyre, P Maass, B Roling… - … on Progress in …, 2009 - pubishingsupport.iopscience.iop.org
A number of basic scientific questions relating to ion conduction in homogeneously
disordered solids are discussed. The questions deal with how to define the mobile ion …

Search for a Grotthuss mechanism through the observation of proton transfer

I Popov, Z Zhu, AR Young-Gonzales, RL Sacci… - Communications …, 2023 - nature.com
The transport of protons is critical in a variety of bio-and electro-chemical processes and
technologies. The Grotthuss mechanism is considered to be the most efficient proton …

The mechanism of the dielectric relaxation in water

I Popov, PB Ishai, A Khamzin, Y Feldman - Physical Chemistry …, 2016 - pubs.rsc.org
Although relating to the same system, the interpretations of the water spectra from Raman
and Dielectric spectroscopy present independent pictures of the nature of water. We show …

Li+ transference numbers in liquid electrolytes obtained by very-low-frequency impedance spectroscopy at variable electrode distances

F Wohde, M Balabajew, B Roling - Journal of The …, 2016 - iopscience.iop.org
The Li+ transference numbers of three different liquid electrolytes for Li-ion batteries were
measured in a symmetrical Li| electrolyte| Li cell by means of very-low-frequency impedance …

New Lithium Chalcogenidotetrelates, LiChT: Synthesis and Characterization of the Li+-Conducting Tetralithium ortho-Sulfidostannate Li4SnS4

T Kaib, S Haddadpour, M Kapitein, P Bron… - Chemistry of …, 2012 - ACS Publications
A new lithium chalcogenidotetrelate, denoted as LiChT phase, with the elemental
combination Li/Sn/S was synthesized as solvent-free and solvent-containing salts. We …

Temperature dependence of the electrical conductivity of imidazolium ionic liquids

J Leys, M Wübbenhorst, C Preethy Menon… - The Journal of …, 2008 - pubs.aip.org
The electrical conductivities of 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids
and of 1-hexyl-3-methylimidazolium ionic liquids with different anions were determined in …

Universal scaling of charge transport in glass-forming ionic liquids

JR Sangoro, C Iacob, A Serghei, C Friedrich… - Physical Chemistry …, 2009 - pubs.rsc.org
Charge transport and glassy dynamics of a variety of glass-forming ionic liquids (ILs) are
investigated in a wide frequency and temperature range by means of broadband dielectric …