Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Heteroleptic diimine–diphosphine Cu (I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and …

Y Zhang, M Schulz, M Wächtler, M Karnahl… - Coordination Chemistry …, 2018 - Elsevier
Photoactive Cu (I) complexes are considered as a promising alternative to traditional noble-
metal complexes that are mainly based on Ru (II) and Ir (III). Therefore, in recent years …

3dd Excited States of Ni(II) Complexes Relevant to Photoredox Catalysis: Spectroscopic Identification and Mechanistic Implications

SI Ting, S Garakyaraghi, CM Taliaferro… - Journal of the …, 2020 - ACS Publications
Synthetic organic chemistry has seen major advances due to the merger of nickel and
photoredox catalysis. A growing number of Ni-photoredox reactions are proposed to involve …

Ruthenium (II) and osmium (II) bis (terpyridine) complexes in covalently-linked multicomponent systems: synthesis, electrochemical behavior, absorption spectra, and …

JP Sauvage, JP Collin, JC Chambron… - Chemical …, 1994 - ACS Publications
1. Introduction A photon is at the same time a quantum of energy and a bit ofinformation. The
interaction of light with “matter” can therefore be used for energy or information purposes …

Helicates as versatile supramolecular complexes

C Piguet, G Bernardinelli, G Hopfgartner - Chemical reviews, 1997 - ACS Publications
The term helicate was introduced by Lehn and coworkers in 1987 for the description of a
polymetallic helical double-stranded complex, in effect a metalcontaining helix. 1 It is formed …

Photoactive mono-and polynuclear Cu (I)–phenanthrolines. A viable alternative to Ru (II)–polypyridines?

N Armaroli - Chemical Society Reviews, 2001 - pubs.rsc.org
Over the past two decades the photochemical and photophysical properties of Cu (I)–
phenanthrolines ([Cu (NN) 2]+) have been investigated in detail. A high degree of control of …

Photochemistry and photophysics of coordination compounds: Copper

N Armaroli, G Accorsi, F Cardinali, A Listorti - … and Photophysics of …, 2007 - Springer
Cu (I) complexes and clusters are the largest class of compounds of relevant photochemical
and photophysical interest based on a relatively abundant metal element. Interestingly …

Highly Luminescent CuI Complexes for Light‐Emitting Electrochemical Cells

N Armaroli, G Accorsi, M Holler, O Moudam… - Advanced …, 2006 - Wiley Online Library
Highly luminescent Cu I complexes with one phenanthroline and one (bis [2‐
(diphenylphosphino) phenyl] ether) ligand show an emission quantum yield of up to 28 …

Rotaxanes incorporating two different coordinating units in their thread: Synthesis and electrochemically and photochemically induced molecular motions

N Armaroli, V Balzani, JP Collin, P Gaviña… - Journal of the …, 1999 - ACS Publications
Three different multicomponent molecular systems have been synthesized by means of the
three-dimensional template effect of copper (I). These systems incorporate both a …

Design of a long-lifetime, earth-abundant, aqueous compatible Cu (I) photosensitizer using cooperative steric effects

CE McCusker, FN Castellano - Inorganic Chemistry, 2013 - ACS Publications
A new homoleptic Cu (I) photosensitizer,[Cu (dsbtmp) 2]+(dsbtmp= 2, 9-di (sec-butyl)-3, 4, 7,
8-tetramethyl-1, 10-phenanthroline), designed to exhibit cooperative steric hindrance …