[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Review of purely 4f and mixed-metal nd-4f single-molecule magnets containing only one lanthanide ion

HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2014 - Elsevier
A very basic tutorial-style introduction to Single-Molecule Magnetism, intended for a general
chemistry audience, is provided. This is followed by a review of the synthesis, structures and …

Relaxation dynamics of dysprosium (III) single molecule magnets

YN Guo, GF Xu, Y Guo, J Tang - Dalton Transactions, 2011 - pubs.rsc.org
Over the past decade, lanthanide compounds have become of increasing interest in the field
of Single Molecule Magnets (SMMs) due to the large inherent anisotropy of the metal ions …

Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Family of Carboxylate- and Nitrate-diphenoxo Triply Bridged Dinuclear NiIILnIII Complexes (Ln = Eu, Gd, Tb, Ho, Er, Y): Synthesis, Experimental and Theoretical …

E Colacio, J Ruiz, AJ Mota, MA Palacios… - Inorganic …, 2012 - ACS Publications
Seven acetate-diphenoxo triply bridged MII-LnIII complexes (MII= NiII and LnIII= Gd, Tb, Ho,
Er, and Y; MII= ZnII and LnIII= HoIII and ErIII) of formula [M (μ-L)(μ-OAc) Ln (NO3) 2], one …

Density functional studies on dinuclear {Ni II Gd III} and trinuclear {Ni II Gd III Ni II} complexes: magnetic exchange and magneto-structural maps

SK Singh, NK Tibrewal, G Rajaraman - Dalton Transactions, 2011 - pubs.rsc.org
Theoretical calculations using density functional methods have been performed on two
dinuclear {NiII–GdIII} and two trinuclear {NiII–GdIII–NiII} complexes having two and three μ …

Syntheses, Structures, and Magnetic Analyses of a Family of Heterometallic Hexanuclear [Ni4M2] (M = Gd, Dy, Y) Compounds: Observation of Slow Magnetic Relaxation in the …

H Ke, L Zhao, Y Guo, J Tang - Inorganic Chemistry, 2012 - ACS Publications
We described the syntheses, crystal structures, and magnetic behavior of a novel series of
heterometallic [Ni4M2][M= Gd (1), Dy (2) and Y (3)] hexanuclear compounds afforded by the …

Syntheses, Structures, and Magnetic Properties of a Family of Heterometallic Heptanuclear [Cu5Ln2] (Ln = Y(III), Lu(III), Dy(III), Ho(III), Er(III), and Yb(III)) Complexes …

V Chandrasekhar, A Dey, S Das, M Rouzières… - Inorganic …, 2013 - ACS Publications
Sequential reaction of the multisite coordination ligand (LH3) with Cu (OAc) 2· H2O, followed
by the addition of a rare-earth (III) nitrate salt in the presence of triethylamine, afforded a …

Heterometallic 3d–4f polyoxometalates: still an incipient field

S Reinoso - Dalton Transactions, 2011 - pubs.rsc.org
Heterometallic 3d–4f polyoxometalates still remain as an almost unexplored class of
polyoxoanions despite showing great potential in fields such as molecular magnetism. This …