Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …
Coordination chemistry on carbon surfaces
MR Axet, O Dechy-Cabaret, J Durand… - Coordination Chemistry …, 2016 - Elsevier
Immobilization of transition metal complexes with catalytic, electronic or luminescent
properties onto solid supports is a theme of intense research. The relatively good knowledge …
properties onto solid supports is a theme of intense research. The relatively good knowledge …
Copper Cluster Size Effect in Methanol Synthesis from CO2
Size-selected Cu n catalysts (n= 3, 4, 20) were synthesized on Al2O3 thin films using mass-
selected cluster deposition. A systematic study of size and support effects was carried out for …
selected cluster deposition. A systematic study of size and support effects was carried out for …
Atomic layer deposition of a submonolayer catalyst for the enhanced photoelectrochemical performance of water oxidation with hematite
Hematite photoanodes were coated with an ultrathin cobalt oxide layer by atomic layer
deposition (ALD). The optimal coating 1 ALD cycle, which amounts to< 1 monolayer of Co …
deposition (ALD). The optimal coating 1 ALD cycle, which amounts to< 1 monolayer of Co …
Size-Dependent Subnanometer Pd Cluster (Pd4, Pd6, and Pd17) Water Oxidation Electrocatalysis
G Kwon, GA Ferguson, CJ Heard, EC Tyo, C Yin… - ACS …, 2013 - ACS Publications
Water oxidation is a key catalytic step for electrical fuel generation. Recently, significant
progress has been made in synthesizing electrocatalytic materials with reduced …
progress has been made in synthesizing electrocatalytic materials with reduced …
Alumina-supported sub-nanometer Pt 10 clusters: amorphization and role of the support material in a highly active CO oxidation catalyst
Catalytic CO oxidation is unveiled on size-selected Pt10 clusters deposited on two very
different ultrathin (≈ 0.5–0.7 nm thick) alumina films:(i) a highly ordered alumina obtained …
different ultrathin (≈ 0.5–0.7 nm thick) alumina films:(i) a highly ordered alumina obtained …
Reaction mechanism for direct propylene epoxidation by alumina-supported silver aggregates: the role of the particle/support interface
Subnanometer Ag aggregates on alumina supports have been found to be active toward
direct propylene epoxidation to propylene oxide by molecular oxygen at low temperatures …
direct propylene epoxidation to propylene oxide by molecular oxygen at low temperatures …
Subnanometer cobalt oxide clusters as selective low temperature oxidative dehydrogenation catalysts
The discovery of more efficient, economical, and selective catalysts for oxidative
dehydrogenation is of immense economic importance. However, the temperatures required …
dehydrogenation is of immense economic importance. However, the temperatures required …
Atomically precise (catalytic) particles synthesized by a novel cluster deposition instrument
C Yin, E Tyo, K Kuchta, B Von Issendorff… - The Journal of chemical …, 2014 - pubs.aip.org
We report a new high vacuum instrument which is dedicated to the preparation of well-
defined clusters supported on model and technologically relevant supports for catalytic and …
defined clusters supported on model and technologically relevant supports for catalytic and …
Computational design of clusters for catalysis
E Jimenez-Izal, AN Alexandrova - Annual review of physical …, 2018 - annualreviews.org
When small clusters are studied in chemical physics or physical chemistry, one perhaps
thinks of the fundamental aspects of cluster electronic structure, or precision spectroscopy in …
thinks of the fundamental aspects of cluster electronic structure, or precision spectroscopy in …