Recent advances in the electrochemically mediated chemical transformation of carbon dioxide

ZQ Yu, M Shi - Chemical Communications, 2022 - pubs.rsc.org
CO2 as a classical C1 unit is often used in the synthesis of high value-added carboxylic
acids and their derivatives in organic synthetic chemistry. There have been many reports in …

Direct synthesis of thioesters from feedstock chemicals and elemental sulfur

H Tang, M Zhang, Y Zhang, P Luo… - Journal of the …, 2023 - ACS Publications
The development of a mild, atom-and step-economical catalytic strategy that effectively
generates value-added molecules directly from readily available commodity chemicals is a …

Partial reductions of carboxylic acids and their derivatives to aldehydes

Z Yang - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
The one-pot reductive synthesis of aldehydes from carboxylic acids and their derivatives
without the formation of alkanol intermediates, in a redox-economical fashion, is …

Sulfonyl chlorides as thiol surrogates for carbon–sulfur bond formation: One-pot synthesis of thioethers and thioesters

T Cellnik, AR Healy - The Journal of Organic Chemistry, 2022 - ACS Publications
A method to synthesize thioethers and thioesters directly from readily available sulfonyl
chlorides is reported. We demonstrate that a transient intermediate formed during phosphine …

CuO Decorated Magnetic Reduced Graphene Oxide Catalyzed Cross-Dehydrogenative Coupling of Thiols and Alkylbenzenes

M Rousta, D Khalili, E Ebrahimi, A Khoy - Catalysis Letters, 2024 - Springer
An efficient CS cross-dehydrogenative coupling (CDC) has been achieved using
rGO/Fe3O4-CuO as a robust nanocatalyst in the presence of TBHP and SDS as a surfactant …

Asymmetric total synthesis of all rugulovasine stereoisomers and preliminary evaluation of their biological properties

F Bartoccini, A Regni, M Retini… - European Journal of …, 2022 - Wiley Online Library
A unified enantioselective synthesis and the biological evaluation of all rugulovasine
stereoisomers are reported. The syntheses are centered on the divergent and …

Ambient-Light-Promoted Stereospecific Synthesis of (Z)-Vinyl Thioesters under Solvent- and Catalyst-Free Conditions

R Wang, JL Yuan, KL Liang, JY Hu, Q Fu… - The Journal of Organic …, 2024 - ACS Publications
An ambient-light-promoted stereospecific olefinic C (sp2)–S bond construction of thioacids
and 1, 1-diarylethenes has been demonstrated, affording various (Z)-vinyl thioesters in 51 …

N-to-S Acyl Transfer as an Enabling Strategy in Asymmetric and Chemoenzymatic Synthesis

WS Jo, BJ Curtis, M Rehan, ML Adrover-Castellano… - JACS Au, 2024 - ACS Publications
The observation of thioester-mediated acyl transfer processes in nature has inspired the
development of novel protein synthesis and functionalization methodologies. The …

Synthesis of the Key Intermediate of SM-406 (Xevinapant) and Its Analogues

Y Zhang, Y Wang, G Xie, J Chen, A Hu… - The Journal of …, 2022 - ACS Publications
Efficient methods for the synthesis of three dipeptide mimetics with diazabicycloalkanone
amino acid scaffolds were developed. Among them, compound 3, which contains a 1, 5 …

Recent advances in continuous flow synthesis of heterocycles

S Goel, M Khulbe, A Aggarwal, A Kathuria - Molecular Diversity, 2021 - Springer
In the current scenario, flow chemistry is emerging as a significant technology in the field of
organic synthesis. This miniaturized protocol including microreactors facilitates excellent …