Organic peroxides in aerosol: key reactive intermediates for multiphase processes in the atmosphere
Organic peroxides (POs) are organic molecules with one or more peroxide (− O–O−)
functional groups. POs are commonly regarded as chemically labile termination products …
functional groups. POs are commonly regarded as chemically labile termination products …
Highly oxygenated organic molecules (HOM) from gas-phase autoxidation involving peroxy radicals: A key contributor to atmospheric aerosol
Highly oxygenated organic molecules (HOM) are formed in the atmosphere via autoxidation
involving peroxy radicals arising from volatile organic compounds (VOC). HOM condense on …
involving peroxy radicals arising from volatile organic compounds (VOC). HOM condense on …
Atmospheric new particle formation and growth: review of field observations
VM Kerminen, X Chen, V Vakkari… - Environmental …, 2018 - iopscience.iop.org
This review focuses on the observed characteristics of atmospheric new particle formation
(NPF) in different environments of the global troposphere. After a short introduction, we will …
(NPF) in different environments of the global troposphere. After a short introduction, we will …
[HTML][HTML] Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds
A Tilgner, T Schaefer, B Alexander… - Atmospheric …, 2021 - acp.copernicus.org
The acidity of aqueous atmospheric solutions is a key parameter driving both the partitioning
of semi-volatile acidic and basic trace gases and their aqueous-phase chemistry. In addition …
of semi-volatile acidic and basic trace gases and their aqueous-phase chemistry. In addition …
Organosulfates in ambient aerosol: state of knowledge and future research directions on formation, abundance, fate, and importance
M Brüggemann, R Xu, A Tilgner… - Environmental …, 2020 - ACS Publications
Organosulfates (OSs), also referred to as organic sulfate esters, are well-known and
ubiquitous constituents of atmospheric aerosol particles. Commonly, they are assumed to …
ubiquitous constituents of atmospheric aerosol particles. Commonly, they are assumed to …
Formation and evolution of molecular products in α-pinene secondary organic aerosol
Much of our understanding of atmospheric secondary organic aerosol (SOA) formation from
volatile organic compounds derives from laboratory chamber measurements, including …
volatile organic compounds derives from laboratory chamber measurements, including …
Biogenic secondary organic aerosols: A review on formation mechanism, analytical challenges and environmental impacts
The review initiates with current state of information on the atmospheric reaction mechanism
of biogenic volatile organic compounds (BVOCs) and its fate in the atmosphere. The plants …
of biogenic volatile organic compounds (BVOCs) and its fate in the atmosphere. The plants …
Hydroxyl radical-induced formation of highly oxidized organic compounds
T Berndt, S Richters, T Jokinen, N Hyttinen… - Nature …, 2016 - nature.com
Explaining the formation of secondary organic aerosol is an intriguing question in
atmospheric sciences because of its importance for Earth's radiation budget and the …
atmospheric sciences because of its importance for Earth's radiation budget and the …
Atmospheric autoxidation is increasingly important in urban and suburban North America
Gas-phase autoxidation—regenerative peroxy radical formation following intramolecular
hydrogen shifts—is known to be important in the combustion of organic materials. The …
hydrogen shifts—is known to be important in the combustion of organic materials. The …
Labile peroxides in secondary organic aerosol
M Krapf, I El Haddad, EA Bruns, U Molteni… - Chem, 2016 - cell.com
Peroxide-containing highly oxygenated molecules (HOMs) are formed upon ozonolysis of
terpenes emitted from the biosphere and are expected to be a major driving force for the …
terpenes emitted from the biosphere and are expected to be a major driving force for the …