Asymmetric synthesis, in which chiral organocatalysts or metal complexes with chiral ligands
are used, has become the most valuable methodology for the preparation of …

The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews …

Sulfoximines are widely used as medicines, agricultural chemicals, chiral precursors, and
chiral ligands in asymmetric synthesis, as well as pivotal intermediates for the construction of …

The enantioselective synthesis of isochroman motifs has been accomplished by palladium
(II)‐catalyzed allylic C− H oxidation from terminal olefin precursors. Critical to the success of …

Chiral sulfur pharmacophores are crucial for drug discovery in bioscience and medicinal
chemistry. While the catalytic asymmetric synthesis of sulfoxides and sulfinate esters with …

Cross-coupling of nitrogen with hydrocarbons under fragment coupling conditions stands to
significantly impact chemical synthesis. Herein, we disclose a C (sp3)–N fragment coupling …

Highly Enantioselective Aldol Reaction with 2-Trimethylsilyloxyfuran: The First Catalytic
Asymmetric Autoinductive Aldol Reaction The authors wish to thank JC Jullian for his help in …

Despite their synthetic significance there is a general lack of asymmetric vinylogous aldol
reactions that tolerate variations of both the silyloxy furans and aldehydes. We have …

An unprecedented cascade vinylogous Mukaiyama 1, 6-MA/MA of 2-silyloxyfurans and
azoalkenes was realized with a Cu (II)/t Bu-Box complex. An array of fused butyrolactones …

Twice as good: The title reaction using the tryptophan‐derived bifunctional organic catalyst 1
has been developed. The reported method led to the synthesis of chiral γ‐substituted …