Reusable N-heterocyclic carbene complex catalysts and beyond: a perspective on recycling strategies

W Wang, L Cui, P Sun, L Shi, C Yue, F Li - Chemical reviews, 2018 - ACS Publications
With the continuous development of N-heterocyclic carbene (NHC) chemistry during the past
decade, NHC metal complexes have gained wide applications in the research field of …

Immobilization of N-heterocyclic carbene compounds: a synthetic perspective

R Zhong, AC Lindhorst, FJ Groche… - Chemical Reviews, 2017 - ACS Publications
Over the course of the past 15 years the success story of N-heterocyclic carbene (NHC)
compounds in organic, inorganic, and organometallic chemistry has been extended to …

Highly efficient synthesis of poly (silylether) s: Access to degradable polymers from renewable resources

H Fouilloux, MN Rager, P Ríos, S Conejero… - Angewandte …, 2022 - Wiley Online Library
The design of new materials with tunable properties and intrinsic recyclability, derived from
biomass under mild conditions, stands as a gold standard in polymer chemistry. Reported …

Cellulose-supported N-heterocyclic carbene-palladium catalyst: Synthesis and its applications in the Suzuki cross-coupling reaction

X Wang, P Hu, F Xue, Y Wei - Carbohydrate polymers, 2014 - Elsevier
A cellulose-supported N-methylimidazole-palladium catalyst (Cell-NHC-Pd) was
synthesized and used for Suzuki cross-coupling reactions between aryl halides and …

“Activated Borane”: A Porous Borane Cluster Polymer as an Efficient Lewis Acid-Based Catalyst

M Lamac, B Urbán, M Horáček, D Buzek… - ACS …, 2023 - ACS Publications
Borane cluster-based porous covalent networks, named activated borane (ActB), were
prepared by cothermolysis of decaborane (14)(nido-B10H14) and selected hydrocarbons …

Polymers from bioderived resources: Synthesis of poly (silylether) s from furan derivatives catalyzed by a salen–Mn (V) complex

S Vijjamarri, S Streed, EM Serum… - Acs Sustainable …, 2018 - ACS Publications
Synthesis of degradable polymers from renewable resources has been a promising way to
replace nonrenewable fossil fuel derived polymers motivated by environmental …

Poly (silyl ether) s (silyl ether copolymers) via hydrosilylation of carbonyl compounds

S Luleburgaz, U Tunca, H Durmaz - Polymer Chemistry, 2023 - pubs.rsc.org
Hydrosilylation of carbonyl compounds gives the corresponding silyl ethers in the presence
of various catalysts. Previously, transition metals and metal halides, such as Ni, NiCl2 …

β-(Z) selectivity control by cyclometalated rhodium (III)–triazolylidene homogeneous and heterogeneous terminal alkyne hydrosilylation catalysts

B Sánchez-Page, J Munarriz, MV Jiménez… - ACS …, 2020 - ACS Publications
The cyclometalated Rh (III)–NHC compounds [Cp* RhI (C, C′)-Triaz](Triaz= 1, 4-diphenyl-3-
methyl-1, 2, 3-triazol-5-ylidene) and [Cp* RhI (C, C′)-Im](Im= 1-phenyl-3-methyl-imidazol-2 …

Hybrid catalysts comprised of graphene modified with rhodium-based N-heterocyclic carbenes for alkyne hydrosilylation

B Sanchez-Page, MV Jiménez… - ACS Applied Nano …, 2020 - ACS Publications
Thermally partially reduced graphene oxide has been covalently modified with 3-methyl-4-
phenyl-1, 2, 3-triazolium salts making use of the epoxy functionalities on the carbon …

Heterogenization of Pd–NHC complexes onto a silica support and their application in Suzuki–Miyaura coupling under batch and continuous flow conditions

A Martínez, JL Krinsky, I Peñafiel, S Castillón… - Catalysis Science & …, 2015 - pubs.rsc.org
The heterogenisation of a new family of Pd–NHC complexes is reported via a
straightforward and efficient synthetic procedure. These silica-immobilised materials were …