Propylene gas is produced worldwide by steam cracking on million‐metric‐ton scale per
year. It serves as a valuable starting material for π‐bond functionalization but is rarely …

Photocatalytic C–C bonds formation is an effective approach to synthesize the significant
drug intermediates diaryl ketones. Herein, a new polyoxometalate-based metal–organic …

Here, we report a set of new polymerization reactions enabled by the 1, 2-regioselective
hydro-and silylcupration of enyne-type propargylic electrophiles. Highly regioregular head …

We report a highly enantioselective intermolecular C− H bond silylation catalyzed by a
phosphoramidite‐ligated iridium catalyst. Under reagent‐controlled protocols …

An elegant Lewis acid catalyzed, protection-free, and straightforward synthetic strategy for
the assembly of a series of sophisticated polycyclic quinoline skeletons employing …

Controlled polymerization of cumulenic monomers represents a promising yet
underdeveloped strategy toward well-defined alkyne polymers. Here we report a …

A cobalt-catalyzed hydroalkynylation of alkenes with alkynyl trifluoroborates is described,
proceeding through a cobalt hydride-mediated radical-polar crossover metal hydrogen-atom …

过渡金属催化反应的蓬勃发展有力地推动了结构多样, 功能丰富的炔类高分子的合成和应用研究
. 从炔烃单体出发合成炔类高分子经典的策略包括:(1) 炔基碳氢(卤) 键活化, 对应偶联聚合;(2) …

Here, we describe the unexpected discovery of a Cu-catalyzed condensation polymerization
reaction of propargylic electrophiles (CPPE) that transforms simple C3 building blocks into …

For years, polyenes with an extensively cross-conjugated backbone have fascinated
chemists by their unique opto-electronic properties and reactivities, but so far only short …