Progress in metallo-supramolecular chemistry creates potential to synthesize functional
nano systems and intelligent materials of increasing complexity. In the past four decades …

Although metallosupramolecular cages are self-assembled from seemingly simple building
blocks, metal ions and organic ligands, architectures of increasingly large size and …

The flexibility of biomolecules enables them to adapt and transform as a result of signals
received from the external environment, expressing different functions in different contexts …

Stimuli-responsive coordination cages allow reversible control over guest binding and
release, relevant for adaptive receptors, carriers, catalysts, and complex systems. Light …

Since the emergence of the concept of chemical topology, interlocked molecular assemblies
have graduated from academic curiosities and poorly defined species to become synthetic …

Multi-component hierarchically porous materials are an emerging class of materials with
tailored compositions, tunable distribution and sophisticated applications. An increasing …

In this review, a comprehensive summary of supramolecular transformations within discrete
coordination-driven supramolecular architectures, including helices, metallacycles …

Half a century after Schill and Lüttringhaus carried out the first directed synthesis of a [2]
catenane, a plethora of strategies now exist for the construction of molecular Hopf links …

Although chiral mechanically interlocked molecules (MIMs) have been synthesised and
studied, enantiopure examples are relatively under-represented in the pantheon of reported …

Conspectus Compounds featuring one-dimensional regular arrangements of stacked metal
complexes and alternating [cation–anion]∞ sequences have raised considerable interest …