Recent developments in catalytic amide bond formation

M Todorovic, DM Perrin - Peptide Science, 2020 - Wiley Online Library
Amide bond forming reactions are critical for both polypeptide synthesis and medicinal
chemistry. Most current approaches for amidation employ stoichiometric activating agents …

Cross‐Coupling of C− H and N− H Bonds: A Hydrogen Evolution Strategy for the Construction of C− N Bonds

L Ravindar, SA Hasbullah, NI Hassan… - European Journal of …, 2022 - Wiley Online Library
The progress in C− N bond construction is significant in synthetic and biological chemistry.
Cross‐dehydrogenative couplings of C− H and N− H motifs serve as a unique class of the …

Metal-free transamidation of secondary amides via selective N–C cleavage under mild conditions

Y Liu, S Shi, M Achtenhagen, R Liu, M Szostak - Organic letters, 2017 - ACS Publications
Nonplanar, electronically destabilized amides have emerged as powerful intermediates in
organic synthesis. We report a highly selective method for transamidation of common …

Sub-stoichiometric 2D covalent organic frameworks from tri-and tetratopic linkers

T Banerjee, F Haase, S Trenker, BP Biswal… - Nature …, 2019 - nature.com
Covalent organic frameworks (COFs) are typically designed by breaking down the desired
network into feasible building blocks-either simple and highly symmetric, or more convoluted …

Copper nanoparticles advance electron mobility of graphene-like boron nitride for enhanced aerobic oxidative desulfurization

P Wu, W Zhu, B Dai, Y Chao, C Li, H Li, M Zhang… - Chemical Engineering …, 2016 - Elsevier
Recently, graphene-like boron nitride (g-BN), has been developed a new application, as a
catalyst for aerobic catalysis, which gives it a passport to catalytic field. However, its way to …

Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes

T Krause, S Baader, B Erb, LJ Gooßen - Nature communications, 2016 - nature.com
Amide bond-forming reactions are of tremendous significance in synthetic chemistry.
Methodological research has, in the past, focused on efficiency and selectivity, and these …

One-pot amide bond formation from aldehydes and amines via a photoorganocatalytic activation of aldehydes

GN Papadopoulos, CG Kokotos - The Journal of Organic …, 2016 - ACS Publications
A mild, one-pot, and environmentally friendly synthesis of amides from aldehydes and
amines is described. Initially, a photoorganocatalytic reaction of aldehydes with di-isopropyl …

Photochemical activation of aromatic aldehydes: synthesis of amides, hydroxamic acids and esters

NF Nikitas, MK Apostolopoulou, E Skolia… - … A European Journal, 2021 - Wiley Online Library
A cheap, facile and metal‐free photochemical protocol for the activation of aromatic
aldehydes has been developed. Utilizing thioxanthen‐9‐one as the photocatalyst and …

Supported Gold Nanoparticles for Efficient α‐Oxygenation of Secondary and Tertiary Amines into Amides

X Jin, K Kataoka, T Yatabe, K Yamaguchi… - Angewandte …, 2016 - Wiley Online Library
Although the α‐oxygenation of amines is a highly attractive method for the synthesis of
amides, efficient catalysts suited to a wide range of secondary and tertiary alkyl amines …

Transamidation of N-acyl-glutarimides with amines

Y Liu, M Achtenhagen, R Liu, M Szostak - Organic & biomolecular …, 2018 - pubs.rsc.org
The development of new transamidation reactions for the synthesis of amides is an
important and active area of research due to the central role of amide linkage in various …