Resonant inelastic X-ray scattering

FMF de Groot, MW Haverkort, H Elnaggar… - Nature Reviews …, 2024 - nature.com
Resonant inelastic X-ray scattering (RIXS) is a powerful technique that combines
spectroscopy and inelastic scattering to probe the electronic structure of materials. RIXS is …

Towards controlling the reversibility of anionic redox in transition metal oxides for high-energy Li-ion positive electrodes

Y Yu, P Karayaylali, D Sokaras, L Giordano… - Energy & …, 2021 - pubs.rsc.org
Anionic redox in positive electrode materials in Li-ion batteries provides an additional redox
couple besides conventional metal redox, which can be harvested to further boost the …

Revealing electronic signatures of lattice oxygen redox in lithium ruthenates and implications for high-energy Li-ion battery material designs

Y Yu, P Karayaylali, SH Nowak, L Giordano… - Chemistry of …, 2019 - ACS Publications
Anion redox in lithium transition-metal oxides such as Li2RuO3 and Li2MnO3 has catalyzed
intensive research efforts to find transition-metal oxides with anion redox that may boost the …

Metal–Ligand Covalency in the Valence Excited States of Metal Dithiolenes Revealed by S 1s3p Resonant Inelastic X-ray Scattering

CB Larsen, K Ledbetter, DR Nascimento… - Journal of the …, 2024 - ACS Publications
Metallo dithiolene complexes with biological and catalytic relevance are well-known for
having strong metal–ligand covalency, which dictates their valence electronic structures. We …

Unoccupied electronic structure of actinide dioxides

JG Tobin, H Ramanantoanina, C Daul, P Roussel… - Physical Review B, 2022 - APS
Ligand field density functional theory calculations of the dioxides of thorium, uranium, and
plutonium have been combined with high-energy-resolution fluorescence detection …

New reflections on hard X-ray photon-in/photon-out spectroscopy

S Lafuerza, M Retegan, B Detlefs, R Chatterjee… - Nanoscale, 2020 - pubs.rsc.org
Analysis of the electronic structure and local coordination of an element is an important
aspect in the study of the chemical and physical properties of materials. This is particularly …

The five-analyzer point-to-point scanning crystal spectrometer at ESRF ID26

P Glatzel, A Harris, P Marion, M Sikora… - Synchrotron …, 2021 - journals.iucr.org
X-ray emission spectroscopy in a point-to-point focusing geometry using instruments that
employ more than one analyzer crystal poses challenges with respect to mechanical design …

Revealing the bonding of solvated Ru complexes with valence-to-core resonant inelastic X-ray scattering

E Biasin, DR Nascimento, BI Poulter, B Abraham… - Chemical …, 2021 - pubs.rsc.org
Ru-complexes are widely studied because of their use in biological applications and
photoconversion technologies. We reveal novel insights into the chemical bonding of a …

L3-edge X-ray spectroscopy of rhodium and palladium compounds

HA Suarez Orduz, L Bugarin, SL Heck… - Synchrotron …, 2024 - journals.iucr.org
L3-edge high-energy-resolution fluorescence-detection X-ray absorption near-edge
structure (XANES) spectra for palladium and rhodium compounds are presented, with focus …

Sulfur Kβ X-ray emission spectroscopy: comparison with sulfur K-edge X-ray absorption spectroscopy for speciation of organosulfur compounds

M Qureshi, SH Nowak, LI Vogt… - Physical Chemistry …, 2021 - pubs.rsc.org
Until recently, sulfur was known as a “spectroscopically silent” element because of a paucity
of convenient spectroscopic probes suitable for in situ chemical speciation. In recent years …