Metalation of a thiocatechol-functionalized Zr (IV)-based metal–organic framework for selective C–H functionalization

H Fei, SM Cohen - Journal of the American Chemical Society, 2015 - ACS Publications
The incorporation of 2, 3-dimercaptoterephthalate (thiocatecholate, tcat) into a highly robust
UiO-type metal–organic framework (MOF) has been achieved via postsynthetic exchange …

The quest for single component molecular metals within neutral transition metal complexes

MFG Velho, RAL Silva, D Belo - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
Twenty years ago, the molecular materials community accomplished a major breakthrough
with the report of the first single component molecular metal (SCMM). Previously it was …

Mechanism of the electrocatalytic reduction of protons with diaryldithiolene cobalt complexes

CS Letko, JA Panetier, M Head-Gordon… - Journal of the …, 2014 - ACS Publications
A series of dimeric cobalt-diaryldithiolene complexes [Co (S2C2Ar2) 2] 2, possessing
various aryl para substituents (OMe, F, Cl, and Br), were studied as electrocatalysts for …

Cyano benzene functionalised Ni and Cu bisdithiolene complexes

AG Costa, G Lopes, S Ribeiro, IC Santos, D Simão… - …, 2023 - pubs.rsc.org
New nickel and copper bisdithiolene complexes were prepared as tetraphenylphosphonium
(Ph4P+) salts,(Ph4P) n [M (3cbdt) 2],[n= 1, 2; M= Ni, Cu; 3cbdt= 3-cyanobenzene-1, 2 …

Redox reactions of nickel, copper, and cobalt complexes with “noninnocent” dithiolate ligands: combined in situ spectroelectrochemical and theoretical study

P Machata, P Herich, K Luspai, L Bucinsky… - …, 2014 - ACS Publications
The redox properties of copper, nickel, and cobalt complexes (MePh3P)[M (bdt) 2] with the
ligand benzene-1, 2-dithiolate (bdt) and synthesized complexes (MePh3P)[M (bdtCl2) 2] …

Enabling single qubit addressability in a molecular semiconductor comprising gold-supported organic radicals

J McGuire, HN Miras, E Richards, S Sproules - Chemical Science, 2019 - pubs.rsc.org
A bis (dithiolene) gold complex is presented as a model for an organic molecular electron
spin qubit attached to a metallic surface that acts as a conduit to electrically address the …

Mixed-Valence Conductors from Ni Bis (diselenolene) Complexes with a Thiazoline Backbone

H Hachem, HB Cui, R Kato, P Alemany… - Inorganic …, 2023 - ACS Publications
Highly conducting, mixed-valence, multi-component nickel bis (diselenolene) salts were
obtained by electrocrystallization of the monoanionic species [Ni (Me-thiazds) 2]− 1 (Me …

Lights and shadows in the challenge of binding acyclovir, a synthetic purine-like nucleoside with antiviral activity, at an apical–distal coordination site in copper (II) …

I Perez-Toro, A Dominguez-Martin… - Journal of Inorganic …, 2015 - Elsevier
Several nucleic acid components and their metal complexes are known to be involved in
crucial metabolic steps. Therefore the study of metal–nucleic acid interactions becomes …

[HTML][HTML] Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor

S Oliveira, D Belo, IC Santos… - Beilstein Journal of …, 2015 - beilstein-journals.org
A dissymmetric TTF-type electron donor, cyanobenzene-ethylenedithio-tetrathiafulvalene
(CNB-EDT-TTF), was obtained in high yield, by a cross-coupling reaction with triethyl …

Thiophene-fused nickel dithiolenes: A synthetic scaffold for highly delocalized π-electron systems

CM Amb, CL Heth, SJ Evenson, KI Pokhodnya… - Inorganic …, 2016 - ACS Publications
A series of thiophene-fused nickel dithiolene complexes have been prepared via synthetic
methods which allow the addition of peripheral aryl groups to the fused thiophene of the …