Synthetic applications of oxidative aromatic coupling—from biphenols to nanographenes
M Grzybowski, B Sadowski… - Angewandte Chemie …, 2020 - Wiley Online Library
Oxidative aromatic coupling occupies a fundamental place in the modern chemistry of
aromatic compounds. It is a method of choice for the assembly of large and bewildering …
aromatic compounds. It is a method of choice for the assembly of large and bewildering …
Multiple helicenes featuring synthetic approaches and molecular structures
A Tsurusaki, K Kamikawa - Chemistry Letters, 2021 - academic.oup.com
Helicenes are attractive non-planar polycyclic aromatic hydrocarbons with unique optical
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …
A Near‐Infrared Absorbing and Emissive Quadruple Helicene Enabled by the Scholl Reaction of Perylene
Herein, we report the synthesis, structural analysis, optical and chiroptical properties of a
novel quadruple helicene, which has two [6] and two [7] helicene moieties fused in a …
novel quadruple helicene, which has two [6] and two [7] helicene moieties fused in a …
Synthesis and characterization of hexapole [7] helicene, a circularly twisted chiral nanographene
Y Zhu, Z Xia, Z Cai, Z Yuan, N Jiang, T Li… - Journal of the …, 2018 - ACS Publications
We report the synthesis and characterization of two hexapole [7] helicenes (H7Hs). Single
crystal X-ray diffraction unambiguously confirms the molecular structure. H7H absorbs light …
crystal X-ray diffraction unambiguously confirms the molecular structure. H7H absorbs light …
Chiral nanographene propeller embedding six enantiomerically stable [5] helicene units
V Berezhnaia, M Roy, N Vanthuyne… - Journal of the …, 2017 - ACS Publications
A one-step synthesis of a nanographene propeller with a D 3-symmetry was obtained
starting from 7, 8-dibromo [5] helicene by Yamamoto nickel (0) couplings. It afforded a chiral …
starting from 7, 8-dibromo [5] helicene by Yamamoto nickel (0) couplings. It afforded a chiral …
Enantioselective synthesis of triple helicenes by cross-cyclotrimerization of a helicenyl aryne and alkynes via dynamic kinetic resolution
A Yubuta, T Hosokawa, M Gon, K Tanaka… - Journal of the …, 2020 - ACS Publications
Optically active triple helicenes (TH-1) were prepared via a palladium-catalyzed
enantioselective cross-cyclotrimerization of two helicenyl arynes 5, which are generated in …
enantioselective cross-cyclotrimerization of two helicenyl arynes 5, which are generated in …
Highly Distorted Multiple Helicenes: Syntheses, Structural Analyses, and Properties
HC Huang, YC Hsieh, PL Lee, CC Lin… - Journal of the …, 2023 - ACS Publications
A series of hexapole helicenes (HHs) and nonuple helicenes (NHs) were prepared from 1,
3, 5-tris [2-(arylethynyl) phenyl] benzene through two steps, namely, iodocyclization and …
3, 5-tris [2-(arylethynyl) phenyl] benzene through two steps, namely, iodocyclization and …
Stereoselective syntheses, structures, and properties of extremely distorted chiral nanographenes embedding hextuple helicenes
M Roy, V Berezhnaia, M Villa… - Angewandte Chemie …, 2020 - Wiley Online Library
We report a molecular design and concept using π‐system elongation and steric effects from
helicenes surrounding a triphenylene core toward stable chiral polycyclic aromatic …
helicenes surrounding a triphenylene core toward stable chiral polycyclic aromatic …
Carbazole‐fused polycyclic aromatics enabled by regioselective scholl reactions
The synthesis of new carbazole‐fused polycyclic aromatics with interesting geometry and
useful properties was explored using Scholl reactions. As found from the Scholl reactions of …
useful properties was explored using Scholl reactions. As found from the Scholl reactions of …
Syntheseanwendungen der oxidativen aromatischen Kupplung–von Biphenolen zu Nanographenen
M Grzybowski, B Sadowski, H Butenschön… - Angewandte …, 2020 - Wiley Online Library
Die oxidative aromatische Kupplung nimmt einen grundlegenden Platz in der modernen
Arenchemie ein. Sie ist das Mittel der Wahl für den Aufbau großer, komplizierter …
Arenchemie ein. Sie ist das Mittel der Wahl für den Aufbau großer, komplizierter …