Synthetic applications of oxidative aromatic coupling—from biphenols to nanographenes

M Grzybowski, B Sadowski… - Angewandte Chemie …, 2020 - Wiley Online Library
Oxidative aromatic coupling occupies a fundamental place in the modern chemistry of
aromatic compounds. It is a method of choice for the assembly of large and bewildering …

Multiple helicenes featuring synthetic approaches and molecular structures

A Tsurusaki, K Kamikawa - Chemistry Letters, 2021 - academic.oup.com
Helicenes are attractive non-planar polycyclic aromatic hydrocarbons with unique optical
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …

A Near‐Infrared Absorbing and Emissive Quadruple Helicene Enabled by the Scholl Reaction of Perylene

SH Pun, KM Cheung, D Yang, H Chen… - Angewandte Chemie …, 2022 - Wiley Online Library
Herein, we report the synthesis, structural analysis, optical and chiroptical properties of a
novel quadruple helicene, which has two [6] and two [7] helicene moieties fused in a …

Synthesis and characterization of hexapole [7] helicene, a circularly twisted chiral nanographene

Y Zhu, Z Xia, Z Cai, Z Yuan, N Jiang, T Li… - Journal of the …, 2018 - ACS Publications
We report the synthesis and characterization of two hexapole [7] helicenes (H7Hs). Single
crystal X-ray diffraction unambiguously confirms the molecular structure. H7H absorbs light …

Chiral nanographene propeller embedding six enantiomerically stable [5] helicene units

V Berezhnaia, M Roy, N Vanthuyne… - Journal of the …, 2017 - ACS Publications
A one-step synthesis of a nanographene propeller with a D 3-symmetry was obtained
starting from 7, 8-dibromo [5] helicene by Yamamoto nickel (0) couplings. It afforded a chiral …

Enantioselective synthesis of triple helicenes by cross-cyclotrimerization of a helicenyl aryne and alkynes via dynamic kinetic resolution

A Yubuta, T Hosokawa, M Gon, K Tanaka… - Journal of the …, 2020 - ACS Publications
Optically active triple helicenes (TH-1) were prepared via a palladium-catalyzed
enantioselective cross-cyclotrimerization of two helicenyl arynes 5, which are generated in …

Highly Distorted Multiple Helicenes: Syntheses, Structural Analyses, and Properties

HC Huang, YC Hsieh, PL Lee, CC Lin… - Journal of the …, 2023 - ACS Publications
A series of hexapole helicenes (HHs) and nonuple helicenes (NHs) were prepared from 1,
3, 5-tris [2-(arylethynyl) phenyl] benzene through two steps, namely, iodocyclization and …

Stereoselective syntheses, structures, and properties of extremely distorted chiral nanographenes embedding hextuple helicenes

M Roy, V Berezhnaia, M Villa… - Angewandte Chemie …, 2020 - Wiley Online Library
We report a molecular design and concept using π‐system elongation and steric effects from
helicenes surrounding a triphenylene core toward stable chiral polycyclic aromatic …

Carbazole‐fused polycyclic aromatics enabled by regioselective scholl reactions

M Zhao, SH Pun, Q Gong, Q Miao - Angewandte Chemie …, 2021 - Wiley Online Library
The synthesis of new carbazole‐fused polycyclic aromatics with interesting geometry and
useful properties was explored using Scholl reactions. As found from the Scholl reactions of …

Syntheseanwendungen der oxidativen aromatischen Kupplung–von Biphenolen zu Nanographenen

M Grzybowski, B Sadowski, H Butenschön… - Angewandte …, 2020 - Wiley Online Library
Die oxidative aromatische Kupplung nimmt einen grundlegenden Platz in der modernen
Arenchemie ein. Sie ist das Mittel der Wahl für den Aufbau großer, komplizierter …