Photons, Excitons, and Electrons in Covalent Organic Frameworks
Covalent organic frameworks (COFs) are created by the condensation of molecular building
blocks and nodes to form two-dimensional (2D) or three-dimensional (3D) crystalline …
blocks and nodes to form two-dimensional (2D) or three-dimensional (3D) crystalline …
The Molecular Nature of Redox-Conductive Metal–Organic Frameworks
J Li, S Ott - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Redox-conductive metal–organic frameworks (RC-MOFs) are a class of porous
materials that exhibit electrical conductivity through a chain of self-exchange reactions …
materials that exhibit electrical conductivity through a chain of self-exchange reactions …
Electronic spin qubit candidates arrayed within layered two-dimensional polymers
Molecular electronic spin qubits are promising candidates for quantum information science
applications because they can be reliably produced and engineered via chemical design …
applications because they can be reliably produced and engineered via chemical design …
Synthesis, hole doping, and electrical properties of a semiconducting azatriangulene-based covalent organic framework
Two-dimensional covalent organic frameworks (2D COFs) containing heterotriangulenes
have been theoretically identified as semiconductors with tunable, Dirac-cone-like band …
have been theoretically identified as semiconductors with tunable, Dirac-cone-like band …
Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching
Electric conductivity in metal-organic frameworks (MOFs) follows either a band-like or a
redox-hopping charge transport mechanism. While conductivity by the band-like mechanism …
redox-hopping charge transport mechanism. While conductivity by the band-like mechanism …
π-Stacks of radical-anionic naphthalenediimides in a metal-organic framework
Radical-ionic metal-organic frameworks (MOFs) have unique optical, magnetic, and
electronic properties. These radical ions, forcibly formed by external stimulus-induced redox …
electronic properties. These radical ions, forcibly formed by external stimulus-induced redox …
Backbone coplanarity manipulation via hydrogen bonding to boost the n-type performance of polymeric mixed conductors operating in aqueous electrolyte
The development of high-performance n-type semiconducting polymers remains a
significant challenge. Reported here is the construction of a coplanar backbone via …
significant challenge. Reported here is the construction of a coplanar backbone via …
Tailoring COFs: Transforming Nonconducting 2D Layered COF into a Conducting Quasi-3D Architecture via Interlayer Knitting with Polypyrrole
Improving the electronic conductivity and the structural robustness of covalent organic
frameworks (COFs) is paramount. Here, we covalently cross-link a 2D COF with polypyrrole …
frameworks (COFs) is paramount. Here, we covalently cross-link a 2D COF with polypyrrole …
2D Conjugated polymer thin films for organic electronics: opportunities and challenges
Abstract 2D conjugated polymers (2DCPs) possess extended in‐plane π‐conjugated lattice
and out‐of‐plane π–π stacking, which results in enhanced electronic performance and …
and out‐of‐plane π–π stacking, which results in enhanced electronic performance and …
Synthesis of ruthenium-based metallo-covalent organic frameworks for efficient photocatalytic ring opening of α-ketoepoxides under visible light
M Wang, Z Li, Q Xiong, A Song, Y Lu, R Wang… - Journal of Catalysis, 2023 - Elsevier
Abstract Two-dimensional (2D) metallo-covalent organic frameworks (MCOFs) have been
regarded as an interesting new class of photoactive materials due to their superior thermal …
regarded as an interesting new class of photoactive materials due to their superior thermal …