o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors

J Shi, L Li, Y Li - Chemical Reviews, 2021 - ACS Publications
Arynes are among the most active organic intermediates and have found numerous
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …

Uncovering the neglected similarities of arynes and donor–acceptor cyclopropanes

DB Werz, AT Biju - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Arynes and donor–acceptor (D–A) cyclopropanes are two classes of strained systems
having the potential for numerous applications in organic synthesis. The last two decades …

C H Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

J Yamaguchi, AD Yamaguchi… - Angewandte Chemie …, 2012 - Wiley Online Library
The direct functionalization of C H bonds in organic compounds has recently emerged as a
powerful and ideal method for the formation of carbon–carbon and carbon–heteroatom …

Funktionalisierung von C‐H‐Bindungen: neue Synthesemethoden für Naturstoffe und Pharmazeutika

J Yamaguchi, AD Yamaguchi, K Itami - Angewandte Chemie, 2012 - Wiley Online Library
Die direkte Funktionalisierung von C‐H‐Bindungen in organischen Molekülen hat sich in
jüngster Zeit zu einer wirksamen und idealen Methode entwickelt, mit der Kohlenstoff …

CO2 Incorporation Reaction Using Arynes:  Straightforward Access to Benzoxazinone

H Yoshida, H Fukushima, J Ohshita… - Journal of the American …, 2006 - ACS Publications
CO2 Incorporation Reaction Using Arynes: Straightforward Access to Benzoxazinone |
Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my …

Arynes in transition‐metal‐free multicomponent coupling reactions

SS Bhojgude, AT Biju - Angewandte Chemie International Edition, 2012 - infona.pl
Let's couple together! The multicomponent reactions involving arynes offer direct access to
unusual heterocyclic scaffolds and 1, 2‐disubstituted arenes. This transition‐metal‐free, one …

Aryne 1, 2, 3-trifunctionalization with aryl allyl sulfoxides

Y Li, D Qiu, R Gu, J Wang, J Shi… - Journal of the American …, 2016 - ACS Publications
An aryne 1, 2, 3-trisubstitution with aryl allyl sulfoxides is accomplished, featuring an
incorporation of C–S, C–O, and C–C bonds on the consecutive positions of a benzene ring …

[PDF][PDF] A Multicomponent Coupling Reaction Induced by Insertion of Arynes into the C O Bond of Formamide

E Yoshioka, S Kohtani, H Miyabe - … Chemie International Edition, 2011 - academia.edu
Aryne compounds are highly reactive intermediates that have been widely used in organic
synthesis.[1, 2] In recent years, studies on aryne-based reactions have achieved some …

Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates

H Yoshida, J Ohshita, A Kunai - Bulletin of the Chemical Society …, 2010 - academic.oup.com
A useful synthetic method for building up multisubstituted arenes of structural complexity and
diversity by use of aromatic reactive intermediates is described. Regardless of the transient …

Synthetic methods for the generation and preparative application of benzyne

T Kitamura - Australian journal of chemistry, 2010 - CSIRO Publishing
Many methods have been developed for generating benzyne. Convenient and reliable
precursors extensively studied so far involve benzenediazonium-2-carboxylate and o …