Over the past 20 years reports of sulfonyl migrations have appeared, frequently described as
'unusual'and 'unexpected'. This comprehensive review compiles, for the first time, sulfonyl …

Molecular modifications have been practiced for more than a century and nowadays they
are widely applied in food, pharmaceutical, or other industries to manipulate the …

A novel distal radical rearrangement of alkoxyphosphine is developed for the first time and
applied to the regioselective radical fluoroalkylphosphorylation of unactivated olefins. By …

A metal‐free and external‐oxidant‐free electrosynthesis of β‐acyloxy‐γ‐selenyl amines was
developed. The cascade reaction is triggered by anodic oxidative generation of electrophilic …

The selective reactivity of carbamate and thiocarbamate toward alkylation and amidation is
reported under stable, high-valent, cost-effective cobalt (III) catalysis. This method reveals …

An efficient and practical route for the synthesis of β-amino sulfides by Lewis acid-mediated
electrophilic thiolative difunctionalization of enimides is disclosed. A series of free phenols …

Aromatic organosilanes bearing C (sp2)–Si bonds have found increasing applications
across the chemical science, yet are mostly produced by atom-uneconomical stoichiometric …

The palladium catalyzed cyclotrimerization of ortho‐silylaryl triflates as aryne precursors is
meanwhile an established method to synthesize polycyclic aromatic hydrocarbons (PAHs) …

Here, we document the reinvention of aryne chemistry with" old" o-diiodoarenes as aryne
progenitors. We have established a NaH-mediated activation strategy for the generation of …

Triazolopyridinone derivatives are of high value in both medicinal and material chemistry.
However, the chiral or hindered triazolopyridinone derivatives remain an underexplored …