Synthetic and mechanistic aspects of sulfonyl migrations
AJ Flynn, A Ford, AR Maguire - Organic & Biomolecular Chemistry, 2020 - pubs.rsc.org
Over the past 20 years reports of sulfonyl migrations have appeared, frequently described as
'unusual'and 'unexpected'. This comprehensive review compiles, for the first time, sulfonyl …
'unusual'and 'unexpected'. This comprehensive review compiles, for the first time, sulfonyl …
Metabolic, toxicological, chemical, and commercial perspectives on esterification of dietary polyphenols: a review
Molecular modifications have been practiced for more than a century and nowadays they
are widely applied in food, pharmaceutical, or other industries to manipulate the …
are widely applied in food, pharmaceutical, or other industries to manipulate the …
Regioselective fluoroalkylphosphorylation of unactivated alkenes by radical‐mediated alkoxyphosphine rearrangement
DT Xie, HL Chen, D Wei, BY Wei, ZH Li… - Angewandte Chemie …, 2022 - Wiley Online Library
A novel distal radical rearrangement of alkoxyphosphine is developed for the first time and
applied to the regioselective radical fluoroalkylphosphorylation of unactivated olefins. By …
applied to the regioselective radical fluoroalkylphosphorylation of unactivated olefins. By …
Electrosynthesis of β‐Acyloxy‐γ‐Selenyl Amines via Migratory Oxyselenation of N‐Acyl Allylamines
K Lin, J Lan, T Zhu - Advanced Synthesis & Catalysis, 2022 - Wiley Online Library
A metal‐free and external‐oxidant‐free electrosynthesis of β‐acyloxy‐γ‐selenyl amines was
developed. The cascade reaction is triggered by anodic oxidative generation of electrophilic …
developed. The cascade reaction is triggered by anodic oxidative generation of electrophilic …
Carbamates: A Directing Group for Selective C–H Amidation and Alkylation under Cp* Co (III) Catalysis
The selective reactivity of carbamate and thiocarbamate toward alkylation and amidation is
reported under stable, high-valent, cost-effective cobalt (III) catalysis. This method reveals …
reported under stable, high-valent, cost-effective cobalt (III) catalysis. This method reveals …
Lewis Acid-Mediated Electrophilic Thiolative Difunctionalization of Enimides: Rapid Access to β-Amino Sulfides
Y Zhang, J Wu, W Qiu, L Liao, B Wang, X Zhao - Organic Letters, 2023 - ACS Publications
An efficient and practical route for the synthesis of β-amino sulfides by Lewis acid-mediated
electrophilic thiolative difunctionalization of enimides is disclosed. A series of free phenols …
electrophilic thiolative difunctionalization of enimides is disclosed. A series of free phenols …
Transition-Metal-Free Silylation of Unactivated C(sp2)–H Bonds with tert-Butyl-Substituted Silyldiazenes
Aromatic organosilanes bearing C (sp2)–Si bonds have found increasing applications
across the chemical science, yet are mostly produced by atom-uneconomical stoichiometric …
across the chemical science, yet are mostly produced by atom-uneconomical stoichiometric …
Palladium‐Catalyzed Cyclization of a Pyryne Precursor to Higher Pyrenylenes
The palladium catalyzed cyclotrimerization of ortho‐silylaryl triflates as aryne precursors is
meanwhile an established method to synthesize polycyclic aromatic hydrocarbons (PAHs) …
meanwhile an established method to synthesize polycyclic aromatic hydrocarbons (PAHs) …
Direct insertion into the C–C bond of unactivated ketones with NaH-mediated aryne chemistry
F Luo, CL Li, P Ji, Y Zhou, J Gui, L Chen, Y Yin… - Chem, 2023 - cell.com
Here, we document the reinvention of aryne chemistry with" old" o-diiodoarenes as aryne
progenitors. We have established a NaH-mediated activation strategy for the generation of …
progenitors. We have established a NaH-mediated activation strategy for the generation of …
Enantiospecific electrochemical rearrangement for the synthesis of hindered triazolopyridinone derivatives
Z Ye, Y Wu, N Chen, H Zhang, K Zhu, M Ding… - Nature …, 2020 - nature.com
Triazolopyridinone derivatives are of high value in both medicinal and material chemistry.
However, the chiral or hindered triazolopyridinone derivatives remain an underexplored …
However, the chiral or hindered triazolopyridinone derivatives remain an underexplored …