Strategies to create hierarchical self-assembled structures via cooperative non-covalent interactions

C Rest, R Kandanelli, G Fernández - Chemical Society Reviews, 2015 - pubs.rsc.org
Cooperative phenomena are common processes involved in the hierarchical self-assembly
of multiple systems in nature, such as the tobacco mosaic virus and a cell's cytoskeleton …

Oligo (phenyleneethynylene) s: Shape‐Tunable Building Blocks for Supramolecular Self‐Assembly

Z Fernández, L Sánchez… - Angewandte Chemie …, 2024 - Wiley Online Library
Abstract Oligo (phenyleneethynylene) s (OPEs) have attracted widespread attention due to
their remarkable (opto) electronic and photophysical properties, which have enabled …

Structural rules for the chiral supramolecular organization of OPE-based discotics: induction of helicity and amplification of chirality

F Garcia, L Sanchez - Journal of the American Chemical Society, 2012 - ACS Publications
A systematic study on the structural rules that regulate the chiral supramolecular
organization of oligo (phenylene ethynylene)(OPE)-based discotics is presented. This study …

Multicomponent hydrogels from enantiomeric amino acid derivatives: helical nanofibers, handedness and self-sorting

B Adhikari, J Nanda, A Banerjee - Soft Matter, 2011 - pubs.rsc.org
In this study, chiral helical nanofibers have been obtained from suitable, co-assembling, two
oppositely charged amino acid based two component hydrogels. An equimolar mixture of an …

Dual-mode chiral self-assembly of cone-shaped subphthalocyanine aromatics

MJ Mayoral, J Guilleme, J Calbo, J Aragó… - Journal of the …, 2020 - ACS Publications
Columnar polymers and liquid crystals obtained from π-conjugated cone-shaped molecules
are receiving increasing interest due to the possibility of obtaining unconventional polar …

The Competitive Aggregation Pathway of an Asymmetric Chiral Oligo(p‐phenyleneethynylene) Towards the Formation of Individual P and M Supramolecular Helical …

Z Fernández, B Fernández, E Quiñoá… - Angewandte Chemie …, 2021 - Wiley Online Library
A complex aggregation pathway towards two diastereomeric P and M supramolecular
helices arises from the aggregation of a short, chiral, and rigid oligo (phenyleneethynylene) …

[PDF][PDF] Cooperative Supramolecular Polymerization and Amplification of Chirality in C3‐Symmetrical OPE‐Based Trisamides

F García, PM Viruela, E Matesanz, E Ortí… - Chemistry–A European …, 2011 - academia.edu
The folding of biopolymers, the binding of oxygen by hemoglobin, and some selected
processes of supramolecular polymerization are model examples of allosteric …

C3‐Symmetrical π‐Scaffolds: Useful Building Blocks to Construct Helical Supramolecular Polymers

Y Dorca, J Matern, G Fernandez… - Israel Journal of …, 2019 - Wiley Online Library
In this review, we highlight some relevant examples of C3‐symmetrical molecules that have
been reported to form supramolecular polymers and helical aggregates. In particular, the …

Chiral information harvesting in helical poly (acetylene) derivatives using oligo (p-phenyleneethynylene) s as spacers

Z Fernández, B Fernández, E Quiñoá, R Riguera… - Chemical …, 2020 - pubs.rsc.org
A chiral harvesting transmission mechanism is described in poly (acetylene) s bearing oligo
(p-phenyleneethynylene) s (OPEs) used as rigid achiral spacers and derivatized with chiral …

Understanding the role of conjugation length on the self-assembly behaviour of oligophenyleneethynylenes

B Matarranz, G Ghosh, R Kandanelli… - Chemical …, 2021 - pubs.rsc.org
Oligophenyleneethynylenes (OPEs) are prominent building blocks with exciting optical and
supramolecular properties. However, their generally small spectroscopic changes upon …