The utilization of visible light to mediate chemical reactions in fluid solutions has
applications that range from solar fuel production to medicine and organic synthesis. These …

Two-dimensional infrared (2D-IR) spectroscopy provides powerful tools to investigate
chemical reaction dynamics in the condensed phase. Correlating excitation and detection …

The rapid development of photo (redox) catalysis within the last decades is remarkable to
the extent that the utilization of light‐driven processes in organic chemistry has become a …

Here, we present a protocol for the determination of cage-escape yields following excited-
state electron transfer between a photosensitizer and a quencher. We describe steps for …

This study reports the results of experiments that probed how solvents affect the
recombination efficiency (F cP) of geminate radical cage pairs. The macroviscosity of …

This study reports a method for correlating the radical recombination efficiencies (F cP) of
geminate radical cage pairs to the properties of the solvent. Although bulk viscosity …

Oxygenated hemoproteins are known to react rapidly with nitric oxide (NO) to produce
peroxynitrite (PN) at the heme site. This process could lead either to attenuation of the …

A purified and highly active form of the non-heme diiron hydroxylase AlkB was investigated
using the diagnostic probe substrate norcarane. The reaction afforded C2 (26%) and C3 …

Time-resolved transient absorption spectroscopy was used to investigate the primary
geminate recombination and cage escape of alkyl radicals in solution over a temperature …

The effect of viscosity on the diffusion efficiency (Fdif) of an organic radical pair in a solvent
cage and the termination mechanism, that is, the selectivity of disproportionation (Disp) and …