The 1, 2-diamine moiety is an ubiquitous structural motif found in a wealth of natural
products, including non-proteinogenic amino acids and alkaloids, in pharmaceutical agents …

The double functionalization of carbon–carbon multiple bonds in one-pot processes has
emerged in recent years as a fruitful tool for the rapid synthesis of complex molecular …

Abstract Silver screen: The AgNO3‐catalyzed carbon phosphorylation of alkenes occurs by
an alkene addition/cyclization cascade. Ag+ reacts with Ph2P (O) H to form the crucial active …

Copper-catalyzed intermolecular aminoazidation of alkenes is described. This novel
methodology provides an efficient approach to vicinal amino azides which can easily be …

Palladium catalysis has been instrumental in the development of the intramolecular
diamination of alkenes. Reagent combinations of a palladium catalyst and iodosobenzene …

Vicinal diamines constitute one the most important functional motif in organic chemistry
because of its wide occurrence in a variety of biological and pharmaceutical molecules. We …

A catalyst-controlled vicinal amino-versus oxy-acetoxylation of alkenes with PhI (OAc) 2 as
the oxidant is described. The divergent synthesis of cyclic ureas and isoureas was achieved …

This review highlights the development of palladium-catalyzed C–H and N–H
functionalization reactions involving indole derivatives. These procedures require …

The RhII‐catalyzed oxyamination and diamination of alkenes generate 1, 2‐amino alcohols
and 1, 2‐diamines, respectively, in good to excellent yields and with complete regiocontrol …

Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines
were enabled by hypervalent iodine (III) reagents such as PhI (OCOR) 2 and PhI (NMs2) 2 …