Recent advances in transition-metal-catalyzed glycosyl cross-coupling reactions

A Chen, B Yang, Z Zhou, F Zhu - Chem Catalysis, 2022 - cell.com
As one of the effective strategies for carbohydrate synthesis, chemical synthesis can
precisely control the structure of sugar chains, thus establishing the structure-activity …

Synthesis of 2-Indolyl C-Glycoside Neopetrosins A and C and Congeners via Ni-Catalyzed Photoreductive Cross-Coupling

Y Xia, Y Wang, Z Zhang, T Gulzar, Y Lin, J Wang… - Organic …, 2023 - ACS Publications
Synthesis of 2-Indolyl C-Glycoside Neopetrosins A and C and Congeners via Ni-Catalyzed
Photoreductive Cross-Coupling | Organic Letters ACS ACS Publications C&EN CAS Find my …

Stereoselective assembly of C-oligosaccharides via modular difunctionalization of glycals

YN Ding, MZ Xu, YC Huang, L Ackermann… - Nature …, 2024 - nature.com
C-oligosaccharides are found in natural products and drug molecules. Despite the
considerable progress made during the last decades, modular and stereoselective synthesis …

Recent Advances and Strategies towards Synthesis of Indolyl and Tryptophan‐C‐Glycoside Scaffolds

R Sangwan, Z Azeem… - Advanced Synthesis & …, 2024 - Wiley Online Library
Recently, C‐glycosidic bonds have emerged as pivotal elementary units present in many
naturally occurring alkaloids as well as in pharmaceutically active molecules. Because of the …

Cobalt's Dual Role in Promoting C3-Glycosylation of Indoles: Unraveling Mechanistic Insights

QQ Mu, AX Guo, X Cai, YY Qin, XL Liu, FZ Ye… - Organic …, 2023 - ACS Publications
In this study, we present a cobalt-catalyzed C3-glycosylation of indoles using
unfunctionalized glycals, yielding 3-indolyl-C-deoxyglycosides. These compounds hold …

Palladium‐Catalysed Norbornene‐Mediated Regioselective Direct C−H Glycosylation of Free (N−H) Pyrrole Derivatives

N Singh Chauhan… - Advanced Synthesis & …, 2024 - Wiley Online Library
A palladium‐catalyzed norbornene‐mediated regioselective direct C− H glycosylation of
free N− H pyrrole and electron‐deficient pyrrole derivatives has been developed. The …

Mild method for the synthesis of α-glycosyl chlorides: A convenient protocol for quick one-pot glycosylation

A Khanam, S Dubey, PK Mandal - Carbohydrate Research, 2023 - Elsevier
A simple and efficient protocol for the preparation of α-glycosyl chlorides within 15–30 min is
described which employs a stable, cheap, and commercially available Trichloroisocyanuric …