The persistent radical effect in organic synthesis

D Leifert, A Studer - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Der “Persistent Radical Effect” in der organischen Chemie

D Leifert, A Studer - Angewandte Chemie, 2020 - Wiley Online Library
Abstract Radikal‐Radikal‐Kupplungen sind nahezu diffusionskontrollierte Prozesse. Daher
sind selektive Kreuzkupplungen zweier unterschiedlicher Radikale schwierig zu realisieren …

Neutral, cationic, and zwitterionic ruthenium (II) atom transfer radical addition catalysts supported by P, N-substituted indene or indenide ligands

RJ Lundgren, MA Rankin, R McDonald… - …, 2008 - ACS Publications
A series of Ru-based complexes supported by P, N-substituted indene or indenide ligands
have been prepared and tested for activity in the atom transfer radical addition of CCl4 to …

Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?: A Fruitful Interplay Anyway: Part 3: Catalysis by Group 10 and 11 …

U Jahn - Radicals in Synthesis III, 2012 - Springer
This review summarizes the current status of transition metal catalyzed reactions involving
radical intermediates in organic chemistry. This part focuses on radical-based methods …

Addition of tetrachloromethane to alkenes catalyzed by copper (I) complexes with N-thioacylamidothiophosphate ligands

A Zazybin, O Osipova, U Khusnutdinova… - Journal of Molecular …, 2006 - Elsevier
The catalytic activity of copper (I) complexes with N-thioacylamidothiophosphate ligands
towards addition reaction of tetrachloromethane to alkenes was investigated. The influence …

Reaction mechanisms Part (i) Radical and radical ion reactions

JM Tanko - Annual Reports Section" B"(Organic Chemistry), 2006 - pubs.rsc.org
This chapter provides a summary of the 2005 literature dealing with the mechanism, and to a
lesser extent kinetics, of reactions involving neutral radicals and radical ions in solution. The …