Cyanide-bridged assemblies with tricyanometalates

T Shiga, N Mihara, M Nihei - Coordination Chemistry Reviews, 2022 - Elsevier
Prussian blue, Fe III 4 [Fe II (CN) 6] 3· nH 2 O (n= 14∼ 16), is one of the most classical mixed-
valence complexes and was used as pigments. Combinations of different metal ions lead to …

Cyanido-Bridged Heterobimetallic Molecular Squares: Low-Dimensional Models of Prussian Blue Analogues and Beyond

MG Alexandru, D Visinescu, J Cano… - Crystal Growth & …, 2023 - ACS Publications
The cyanido-bridged square-like molecules with d/f metal ions occupying the corners of the
square are considered molecular models of the Prussian Blue Analogues (PBAs) because …

Heterobimetallic cyanide-bridged Fe III (μ-CN) M II complexes (M= Mn and Cu): synthesis, structure and magnetism

S Ahmed, A Kumar, N Mukhopadhyay, F Lloret… - New Journal of …, 2022 - pubs.rsc.org
A controlled reaction in DMF/CH3CN between a facially disposed tricyanide-containing
building block (nBu4N)[FeIII (Tp)(CN) 3](Tp (–)= tris (pyrazol-1-yl) borate anion) and tailor …

A rare isostructural series of 3d–4f cyanido-bridged heterometallic squares obtained by assembling [Fe III {HB (pz) 3}(CN) 3]− and Ln III ions: synthesis, X-ray structure …

MG Alexandru, D Visinescu, B Cula, S Shova… - Dalton …, 2021 - pubs.rsc.org
A new series of cyanido-bridged {FeIIILnIII} 2 neutral molecular squares of general formula
[Fe {HB (pz) 3}(CN)(μ-CN) 2Ln (NO3) 2 (pyim)(Ph3PO)] 2· 2CH3CN [Ln= Ce (1), Pr (2), Nd …

Cyanido-bridged {Fe III Ln III} heterobimetallic chains assembled through the [Fe III {HB (pz) 3}(CN) 3]− complex as metalloligand: synthesis, crystal structure and …

D Visinescu, MG Alexandru, DG Dumitrescu… - …, 2021 - pubs.rsc.org
A new series of cyanido-bridged {FeIIILnIII} heterobimetallic chains of general formula {[(NC)
FeIII {HB (pz) 3}(μ-CN) 2LnIII (bpdo)(NO3) 2 (H2O)]· CH3CN} n [HB (pz) 3−= hydrotris …

Slow relaxation of the magnetization in a {CoIIIMnIII} heterometallic brick-wall network

MG Alexandru, D Visinescu, S Shova, SE Stiriba… - Polyhedron, 2021 - Elsevier
The use of the cyanide-bearing dicobalt (III) complex (PPh 4) 2 [Co 2 III (μ− 2, 5-dpp)(CN) 8]
as a metalloligand towards [Mn (salen)(H 2 O)] ClO 4 afforded the heterobimetallic two …

X-ray structure and magnetic properties of heterobimetallic chains based on the use of an octacyanidodicobalt (III) complex as metalloligand

MG Alexandru, D Visinescu, S Shova, A Bentama… - Magnetochemistry, 2020 - mdpi.com
The assembly of [Co2III (μ-2, 5-dpp)(CN) 8] 2− anions and [MII (CH3OH) 2 (DMSO) 2] 2+
cations resulted into the formation of two heterobimetallic 1D coordination polymers of …