Potential optical functional crystals with large birefringence: Recent advances and future prospects

A Tudi, S Han, Z Yang, S Pan - Coordination Chemistry Reviews, 2022 - Elsevier
Birefringence is one of key performance for optical functional crystals owing to their
indispensable role in angle phase-matching or adjusting the polarization of light. In the past …

Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials

X Liu, YC Yang, MY Li, L Chen, LM Wu - Chemical Society Reviews, 2023 - pubs.rsc.org
We define the anisotropic structure building unit that encompasses diverse chemical bonds
(ABUCB). The ABUCB is highly likely to cause anisotropy in both crystallographic structure …

Strong Nonlinearity Induced by Coaxial Alignment of Polar Chain and Dense [BO3] Units in CaZn2(BO3)2

M Mutailipu, F Li, C Jin, Z Yang… - Angewandte Chemie …, 2022 - Wiley Online Library
Discovery of new efficient nonlinear optical (NLO) materials with large second‐order
nonlinearity for the short‐wave ultraviolet spectral region (λPM≤ 266 nm, PM= phase …

Bright Green Emission from Self-Trapped Excitons Triggered by Sb3+ Doping in Rb4CdCl6

J Jin, Y Peng, Y Xu, K Han, A Zhang… - Chemistry of …, 2022 - ACS Publications
Sb3+ with stereochemically active lone pair 5 s 2 electrons is overwhelming in the doping
engineering of the luminescent metal halides, and it usually leads to extrinsic self-trapped …

Enhancement of birefringence in borophosphate pushing phase-matching into the short-wavelength region

W Zhang, J Huang, S Han, Z Yang… - Journal of the American …, 2022 - ACS Publications
Borophosphates are very known for the short ultraviolet (UV) cutoff edge and have become
the promising UV and deep-UV functional crystals candidates; however, tetrahedral [PO4] …

Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters

C Jin, F Li, B Cheng, H Qiu, Z Yang, S Pan… - Angewandte …, 2022 - Wiley Online Library
Polarization modulation of deep‐UV light is of significance to current technologies, and to
this end, the birefringent crystal has emerged as an invaluable material as it allows for …

(NH4)3B11PO19F3: a deep-UV nonlinear optical crystal with unique [B5PO10F] layers

B Cheng, Z Li, Y Chu, A Tudi, M Mutailipu… - National Science …, 2022 - academic.oup.com
Deep-ultraviolet (DUV) nonlinear optical (NLO) crystals that can extend the output range of
coherent light below 200 nm are pivotal materials for solid-state lasers. To date, KBe2BO3F2 …

Local polarity-induced assembly of second-order nonlinear optical materials

Y Li, J Luo, S Zhao - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Second-order nonlinear optical (NLO) materials, producing coherent light by the
cascaded frequency conversion, are current hot topics in material chemistry and optics, as …

Aluminoborates as nonlinear optical materials

J Jiao, M Zhang, S Pan - Angewandte Chemie, 2023 - Wiley Online Library
Abstract Ultraviolet (UV) and Deep‐UV (DUV, λ< 200 nm) nonlinear optical (NLO) materials
play a significant role to convert the wavelength of laser for producing UV/DUV coherent …

Guanidinium fluorooxoborates as efficient metal-free short-wavelength nonlinear optical crystals

C Jin, H Zeng, F Zhang, H Qiu, Z Yang… - Chemistry of …, 2021 - ACS Publications
Metal-free borates have emerged as a new class of solid-state chemistry and related
crystalline materials with high performance. However, the discovery of metal-free borate …